Luminescence from TiO2 Nanotubes and Related Nanostructures Investigated Using Synchrotron X-Ray Absorption Near-Edge Structure and X-Ray Excited Optical Luminescence

Lijia Liu, T. Sham
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引用次数: 2

Abstract

Understanding the optical property of nanostructured TiO2 is crucial for their use in a variety of applications such as solar cells, photocatalysis, and light emitting devices. Herein, we introduce the use of synchrotron radiation-based spectroscopic techniques: X-ray absorption near-edge structure (XANES) and X-ray excited optical luminescence (XEOL) in analyzing the luminescence properties of anodized TiO2 nanotubes (TiO2 NT) and related materials. A description on the spectroscopic technique is first given, including conventional XANES-XEOL combined analysis and a more recently developed 2D XANES-XEOL probing technique. We then discuss several examples of analyzing the luminescence mechanism of TiO2 NT using XANES and XEOL technique, which are the phase transformation accompanied luminescence, luminescence from TiO2 NT hierarchical structure, and metal particle–coated TiO2 NT.
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利用同步加速器x射线吸收近边结构和x射线激发光学发光研究TiO2纳米管和相关纳米结构的发光
了解纳米结构TiO2的光学性质对于其在太阳能电池、光催化和发光器件等各种应用中的应用至关重要。在此,我们介绍了基于同步辐射的光谱技术:x射线吸收近边结构(XANES)和x射线激发光学发光(XEOL)来分析阳极氧化TiO2纳米管(TiO2 NT)和相关材料的发光特性。首先介绍了光谱技术,包括传统的XANES-XEOL联合分析和最近开发的二维XANES-XEOL探测技术。然后讨论了利用XANES和XEOL技术分析TiO2 NT发光机理的几个例子,分别是相变伴随发光、TiO2 NT分层结构发光和金属颗粒包覆TiO2 NT。
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