Kinetic Modeling of Vitamin C (Ascorbic Acid) Degradation in Blanched Commonly Consumed Salad Vegetables Using Computer Simulation Analysis

E. Awagu, E. Ekanem, A. M. Kolo, M. Adamu
{"title":"Kinetic Modeling of Vitamin C (Ascorbic Acid) Degradation in Blanched Commonly Consumed Salad Vegetables Using Computer Simulation Analysis","authors":"E. Awagu, E. Ekanem, A. M. Kolo, M. Adamu","doi":"10.9790/5736-1004015966","DOIUrl":null,"url":null,"abstract":"Vitamin C (ascorbic acid) is one of the most important and popular vitamins, and is contained in most fruits and vegetables; the problem with vitamin C is its easy degradation during processing. In this study, the degradation kinetics of vitamin C was determined in Lettuce and Cabbage, and the processing treatment considered was blanching at 70 0 C of water differently for 5, 10, 15, 20,25,30,35 and 40 minutes. Samples were dried in mild temperature (15–20 0 C) and ground to find dust and High Pressure liquid chromatographic (HPLC) was used for determination of the AA of vegetable salad samples which consisted of an isocratic elution procedure with UV-Visible detection at 245nm. The rate constants were calculated for both vegetable salad samples under the same processing method using the integrated law method; half-life was also calculated. Degradation of ascorbic acid in Lettuce and Cabbage under the same pretreatment procedure followed the firstorder kinetic model, as the coefficient of determination (R 2 -value) were 0.8981 and 0.9785 respectively. The rate constant of ascorbic acid degradation for Lettuce and Cabbage under the same blanching conditions were 0.099 min-1 and 0.088 min-1 respectively. The half-life of Lettuce and Cabbage were 420.0892 and 472.6004 seconds respectively. The most appropriate vegetable salad under the blanching pretreatment procedure is the cabbage because its rate constant depicted from the model equations was lower, and the half life longer, hence, slower rate of degradation. The first order forecast (Ln(C)), was 0.657964 for Lettuce and 1.330017 for Cabbage, which further authenticate that blanched Lettuce degradation was higher than Cabbage under the same pretreatment conditions.","PeriodicalId":14488,"journal":{"name":"IOSR Journal of Applied Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2017-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"11","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"IOSR Journal of Applied Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.9790/5736-1004015966","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 11

Abstract

Vitamin C (ascorbic acid) is one of the most important and popular vitamins, and is contained in most fruits and vegetables; the problem with vitamin C is its easy degradation during processing. In this study, the degradation kinetics of vitamin C was determined in Lettuce and Cabbage, and the processing treatment considered was blanching at 70 0 C of water differently for 5, 10, 15, 20,25,30,35 and 40 minutes. Samples were dried in mild temperature (15–20 0 C) and ground to find dust and High Pressure liquid chromatographic (HPLC) was used for determination of the AA of vegetable salad samples which consisted of an isocratic elution procedure with UV-Visible detection at 245nm. The rate constants were calculated for both vegetable salad samples under the same processing method using the integrated law method; half-life was also calculated. Degradation of ascorbic acid in Lettuce and Cabbage under the same pretreatment procedure followed the firstorder kinetic model, as the coefficient of determination (R 2 -value) were 0.8981 and 0.9785 respectively. The rate constant of ascorbic acid degradation for Lettuce and Cabbage under the same blanching conditions were 0.099 min-1 and 0.088 min-1 respectively. The half-life of Lettuce and Cabbage were 420.0892 and 472.6004 seconds respectively. The most appropriate vegetable salad under the blanching pretreatment procedure is the cabbage because its rate constant depicted from the model equations was lower, and the half life longer, hence, slower rate of degradation. The first order forecast (Ln(C)), was 0.657964 for Lettuce and 1.330017 for Cabbage, which further authenticate that blanched Lettuce degradation was higher than Cabbage under the same pretreatment conditions.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
用计算机模拟分析热漂后常见沙拉蔬菜中维生素C(抗坏血酸)降解的动力学模型
维生素C(抗坏血酸)是最重要和最受欢迎的维生素之一,大多数水果和蔬菜中都含有维生素C;维生素C的问题在于它在加工过程中容易降解。在本研究中,测定了生菜和卷心菜中维生素C的降解动力学,并考虑了在70 - 0℃的水下分别焯水5、10、15、20、25、30、35和40 min的加工处理。样品在15-20℃的温和温度下干燥,研磨以寻找粉尘,采用高压液相色谱法(HPLC)测定蔬菜沙拉样品中的AA,该方法采用等温洗脱法,紫外可见检测波长为245nm。采用积分律法计算了两种蔬菜沙拉样品在相同处理方法下的速率常数;还计算了半衰期。在相同的预处理条件下,生菜和白菜中抗坏血酸的降解符合第一种动力学模型,决定系数(r2值)分别为0.8981和0.9785。在相同的焯水条件下,生菜和白菜抗坏血酸降解速率常数分别为0.099 min-1和0.088 min-1。生菜和卷心菜的半衰期分别为420.0892和472.6004秒。在焯水预处理条件下,白菜的速率常数较低,半衰期较长,降解速度较慢,是最合适的蔬菜沙拉。生菜的一级预测Ln(C)为0.657964,大白菜的一级预测Ln(C)为1.330017,进一步证明在相同预处理条件下,焯水生菜的降解率高于大白菜。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
自引率
0.00%
发文量
0
期刊最新文献
Enhancement of Photocatalytic activity of γ- Bi2MoO6 with Graphite flake under Visible light irradiation Comaprison of Iron Nanowires Fabricated via Porous Anodic Aluminium Oxide Template by a.c and d.c. Electrodeposition Metal Complexes of quinolin-8-yl (1, 3-benzoxazol-2-ylsulfanyl) acetate: Spectral, XRD, thermal, molecular docking and biological evaluation Applications of Amberlite XAD based Chelating resins in Online Pre concentration of metal ions Synthesis of Photoconducting Non-linear Optical Co-Polymer of 2-Methacryloyl-1-(4’-nitro-4-azo-1’Phenyl) Salicylic acid With Methylacrylate
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1