{"title":"Urey-Bradley-Kraftkonstanten und andere Schwingungseigenschaften des Trithiocarbonat-Ions","authors":"B. Krebs , A. Müller","doi":"10.1016/0371-1951(66)80151-0","DOIUrl":null,"url":null,"abstract":"<div><p>Urey-Bradley force constants, Coriolis coupling coefficients, and mean amplitudes of vibration were calculated for the CS<sub>3</sub><sup>2−</sup> ion from infra-red and Raman spectroscopic data. The force constants are in accordance with orbital valence force field values. The calculated values for the coupling coefficients and the vibration amplitudes were found to be very similar to the corresponding values for BCl<sub>3</sub>.</p></div>","PeriodicalId":101180,"journal":{"name":"Spectrochimica Acta","volume":"22 8","pages":"Pages 1532-1535"},"PeriodicalIF":0.0000,"publicationDate":"1966-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0371-1951(66)80151-0","citationCount":"8","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Spectrochimica Acta","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0371195166801510","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 8
Abstract
Urey-Bradley force constants, Coriolis coupling coefficients, and mean amplitudes of vibration were calculated for the CS32− ion from infra-red and Raman spectroscopic data. The force constants are in accordance with orbital valence force field values. The calculated values for the coupling coefficients and the vibration amplitudes were found to be very similar to the corresponding values for BCl3.
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