The Nickel Production Methods from Laterites and the Greek Ferronickel Production among Them

Emmanouil N. Zevgolis, Konstantinos Daskalakis
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引用次数: 5

Abstract

Primary world nickel production in 2020 was 2430.7 kt Ni; 69% (1677.7 kt) of them came from oxidized nickel ores (laterites) and 31% from sulfides. Production-wise, 87.7% of the 1677.7 kt came from pyrometallurgical and 12.3% from hydrometallurgical processes. For a long time, Fe-Ni had a 20–40% Ni analysis, but in 2006 a new Fe-Ni quality came into the scene. This is the nickel pig iron (NPI) with 2.5–5.5% Ni that comes from laterite smelting in the blast furnace (B/F). Eventually, the advantages of the R/K-E/F process led to its dispersion in China and Indonesia and resulted in an NPI production with 3–12% Ni. The NPI production in these two countries climbed from zero in 2000, to 1060 kt Ni in 2020 and also stainless-steel production from 5.5% to 67.2%, respectively, of the world’s SS production. The integration of Ni industry with SS production, the economy of scale, the low labor cost, the high Ni content of Indonesian laterite, and the loose environmental laws, reduced significantly the NPI production cost. The addition of SS and/or electric energy production units for cost reduction has been adapted from other Fe-Ni producers, as well. Hellenic Minerals in Cyprus after two years of successful industrial tests is in the commissioning state of a Heap Leaching-Solvent Extraction-Crystallizer (HL-SX-CR) unit for NiSO4.6H2O production. The high demand for Ni and NiSO4.6H2O in the last few years has changed the prospects of Ni laterite hydrometallurgical processing. Regarding the R/K-E/F process used in Greek Fe-Ni, it is characterized by its worldwide acceptance and reliability (more than 77% of world Fe-Ni production comes from this process). Other advantages are the use of all types of laterites and fuels, it has a high metallurgical recovery, and the plant has its own port. However, it is a high energy-consuming process, and it does not recover Co. The Greek laterite, in particular, has the lowest Ni% among global Fe-Ni producers and because of this, electric energy (MWh/t Ni) and wages (wages/t Ni) per ton of Ni are high, making Larco’s viability difficult. The only way to overcome the issue with specific electricity consumption is to enrich the local ores by blending them with imported high grade Ni ores. Other negatives were the excessive electric energy price it had to pay to a dominant energy supplier and the very frequent changes of its administration.
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红土制镍方法及其中希腊镍铁的生产
2020年世界初级镍产量为2430.7 kt Ni;其中69% (1677.7 kt)来自氧化镍矿(红土),31%来自硫化物。在产量方面,1677.7 kt中有87.7%来自火法冶金,12.3%来自湿法冶金。很长一段时间,Fe-Ni有20-40%的Ni分析,但在2006年,一种新的Fe-Ni质量进入了现场。这是含镍2.5-5.5%的镍生铁(NPI),来自于高炉红土冶炼(B/F)。最终,R/K-E/F工艺的优势导致其在中国和印度尼西亚分散,并导致了3-12% Ni的NPI生产。这两个国家的NPI产量从2000年的零上升到2020年的1060万吨镍,不锈钢产量也从占世界SS产量的5.5%上升到67.2%。镍产业与SS生产的整合、规模经济、低廉的劳动力成本、印尼红土的高镍含量以及宽松的环境法规,显著降低了NPI生产成本。为了降低成本,还采用了其他Fe-Ni生产商的SS和/或电能生产装置。塞浦路斯Hellenic Minerals公司经过两年成功的工业测试,目前正处于用于生产NiSO4.6H2O的堆浸-溶剂萃取-结晶器(HL-SX-CR)装置的调试状态。近年来对镍和NiSO4.6H2O的高需求改变了镍红土湿法冶金的前景。关于希腊Fe-Ni中使用的R/K-E/F工艺,其特点是世界范围内的接受和可靠性(世界上77%以上的Fe-Ni生产来自该工艺)。其他优点是利用各种红土和燃料,它具有高的冶金回收率,并且工厂有自己的港口。然而,这是一个高能耗的过程,并且不能回收Co.特别是希腊红土,在全球Fe-Ni生产商中具有最低的Ni%,因此,每吨Ni的电能(MWh/t Ni)和工资(工资/t Ni)很高,使Larco的生存能力变得困难。克服特定电力消耗问题的唯一方法是将当地矿石与进口的高品位镍矿石混合,以丰富当地矿石。其他不利因素是,它必须向占主导地位的能源供应商支付过高的电力价格,以及它的管理部门经常变动。
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