Effect of Graphite and Copper Nano-Particles on Free Volume Properties of PVC/NBR Blends Studied by Pal Spectroscopy

E. Gomaa, E. H. Ali
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Abstract

Positron Annihilation Lifetime (PAL) spectroscopy has been used to investigate the effect of different concentrations of graphite and copper nano-particles in polyvinylchloride (PVC)/ butadiene-acrylonitrile copolymer (NBR) blends on free volume properties of PVC/NBR nano composites. However, the miscibility of PVC/NBR blends was investigated. The free-volume properties showed a negative deviation from linear additive relationship indicating miscibility of two blends. In additions, this research to confirm the results of the previous study on the same samples through the correlation between positron annihilation parameters and some of the properties studied.
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用Pal光谱研究了石墨和铜纳米颗粒对PVC/NBR共混物自由体积性能的影响
利用正电子湮没寿命(PAL)光谱研究了不同浓度的石墨和纳米铜对聚氯乙烯(PVC)/丁二烯-丙烯腈共聚物(NBR)共混物自由体积性能的影响。然而,研究了聚氯乙烯/丁腈橡胶共混物的混相。自由体积性能与线性加性关系呈负偏差,表明两种共混物具有混相性。此外,本研究通过正电子湮灭参数与所研究的某些性质之间的相关性,证实了前人在相同样品上的研究结果。
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