Proton transfer mechanism in the ionic methanol dimer

PhysChemComm Pub Date : 1999-01-01 DOI:10.1039/A903329G
S. Martrenchard, G. Grégoire, C. Dedonder-Lardeux, C. Jouvet, D. Solgadi
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引用次数: 13

Abstract

Intracluster proton transfer reaction in the methanol ionic dimer has been re-investigated using VUV ionization with synchrotron radiation. The energetic thresholds of the proton transfer issued from the methyl group or the hydroxyl group have been obtained. These results are discussed in view of previous calculations and experiments
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离子甲醇二聚体中的质子转移机理
用同步辐射紫外电离法重新研究了甲醇离子二聚体的簇内质子转移反应。从甲基或羟基发出的质子转移的能量阈值已经得到。结合以往的计算和实验,对这些结果进行了讨论
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