{"title":"Reciprocal relations for chemical oscillators","authors":"V. Lesnikov","doi":"10.30970/jps.27.2001","DOIUrl":null,"url":null,"abstract":"it was pointed out that for thermal hydrodynamic (cid:29)uctuations in open hydrodynamic steady states (OHSS) the determining factor for derivation of reciprocal relations is not the principle of microscopic reversibility, but the presence or absence of a (cid:29)ux. In the present work this idea is applied to open chemical steady states (OCSS), where chemical oscillations are possible. The behavior of concentration (cid:29)uctuations when there are no macroscopic oscillations yet is considered. The reciprocal relations for such OCSS are found.","PeriodicalId":43482,"journal":{"name":"Journal of Physical Studies","volume":"8 1","pages":""},"PeriodicalIF":0.7000,"publicationDate":"2023-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Physical Studies","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.30970/jps.27.2001","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"PHYSICS, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
it was pointed out that for thermal hydrodynamic (cid:29)uctuations in open hydrodynamic steady states (OHSS) the determining factor for derivation of reciprocal relations is not the principle of microscopic reversibility, but the presence or absence of a (cid:29)ux. In the present work this idea is applied to open chemical steady states (OCSS), where chemical oscillations are possible. The behavior of concentration (cid:29)uctuations when there are no macroscopic oscillations yet is considered. The reciprocal relations for such OCSS are found.
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