{"title":"Research progress on design, synthesis and performance of energetic polynitro hexaazaisowurtzitane derivatives: Towards improved CL-20 analogues","authors":"Vladimir V. Parakhin, Gennady A. Smirnov","doi":"10.1016/j.fpc.2023.05.006","DOIUrl":null,"url":null,"abstract":"<div><p>In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.</p></div>","PeriodicalId":100531,"journal":{"name":"FirePhysChem","volume":"4 1","pages":"Pages 21-33"},"PeriodicalIF":3.6000,"publicationDate":"2024-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667134423000317/pdfft?md5=f0b981ce4869f4e2cb06666b7c0c7581&pid=1-s2.0-S2667134423000317-main.pdf","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"FirePhysChem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667134423000317","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2023/5/25 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.
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