Design and Retrofitting of Ultrasound Intensified and Ionic Liquid Catalyzed In Situ Algal Biodiesel Production

S. Shrikhande, G. Deshpande, A. N. Sawarkar, Z. Ahmad, D. Patle
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引用次数: 13

Abstract

In this study, new processes are designed for ultrasound assisted in situ algal biodiesel production using ionic liquid catalyst. Process retrofitting is then conducted using a divided-wall column (DWC) and multistage vapor recompression (MVR). Later, comparative analysis in terms of capital cost, cost of manufacturing (COM), cost of biodiesel, and carbon emission is presented. This study shows that the biodiesel cost is linearly dependent on the cost of feedstock and process economics can be improved by converting glycerol to triacetin. The process with DWC and MVR resulted in a significant saving in COM (13.84%), biodiesel cost (18.24%), utility cost (45.44%) and carbon emissions (45.84%) than those in its counterpart. New major contributions of this work are 1) process design for a novel ultrasound assisted and ionic liquid catalyzed algal biodiesel production, 2) implementation of DWC and MVR and 3) investigation of the uncertainty in the thermodynamic property.
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超声强化离子液体催化原位生产藻类生物柴油的设计与改造
本研究设计了超声辅助离子液体催化剂原位生产藻类生物柴油的新工艺。然后使用分壁塔(DWC)和多级蒸汽再压缩(MVR)进行工艺改造。然后,从资金成本、制造成本、生物柴油成本和碳排放等方面进行了比较分析。该研究表明,生物柴油的成本与原料成本呈线性关系,通过将甘油转化为三乙酸酯可以提高工艺经济性。采用DWC和MVR的工艺比采用DWC和MVR的工艺在总成本(13.84%)、生物柴油成本(18.24%)、公用事业成本(45.44%)和碳排放(45.84%)方面显著节省。本工作的主要贡献有:1)超声辅助离子液体催化藻类生物柴油生产的工艺设计;2)DWC和MVR的实现;3)热力学性质不确定性的研究。
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