Wear and Corrosion Resistance Analysis of FeCoNiTiAlx High-Entropy Alloy Coatings Prepared by Laser Cladding

Zhaolei Sun, Mingyuan Zhang, Gaoqi Wang, Xuefeng Yang, Shouren Wang
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引用次数: 10

Abstract

FeCoNiTiAlx (x = 0, 0.5, 1) high-entropy alloy coatings were prepared by laser cladding technology. The phase, microstructure, hardness, wear resistance and corrosion resistance were tested and analyzed. The results showed Al element promoted the conversion from the FCC phase to the BCC phase. The coating presented dendritic structure due to the addition of the Al element, while the number of dendrites increased. And the average hardness of the coating increased from 204 to 623 HV. The addition of the Al element increases the corrosion current density of the coating from 1.270 × 10−5 to 3.489 × 10−5 A/cm2. The wear rate of the coatings decreases with the increase of Al content according to dry friction and wear, which indicates the wear resistance of the coating was improved by adding the Al element. According to the corrosion wear test in 3.5% NaCl solution, it can be found that the wear rate of the coating increases firstly and then decreases with the addition of the Al element, which indicates that the addition of the Al element intensifies the wear of the coating in 3.5% NaCl solution.
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激光熔覆法制备FeCoNiTiAlx高熵合金涂层的耐磨损和耐腐蚀性能分析
采用激光熔覆技术制备FeCoNiTiAlx (x = 0,0.5, 1)高熵合金涂层。对合金的相、组织、硬度、耐磨性和耐腐蚀性进行了测试和分析。结果表明,Al元素促进了FCC相向BCC相的转化。Al元素的加入使涂层呈现枝晶结构,枝晶数量增加。镀层的平均硬度由204 HV提高到623 HV。Al元素的加入使镀层的腐蚀电流密度从1.270 × 10−5增加到3.489 × 10−5 A/cm2。从干摩擦磨损的角度看,涂层的磨损率随Al含量的增加而降低,表明Al元素的加入提高了涂层的耐磨性。通过3.5% NaCl溶液中的腐蚀磨损试验可以发现,随着Al元素的加入,涂层的磨损速率先增大后减小,说明在3.5% NaCl溶液中,Al元素的加入加剧了涂层的磨损。
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