Prediction of yttrium, lanthanum, cerium, and neodymium leaching recovery from apatite concentrate using artificial neural networks

E. Jorjani, A.H. Bagherieh, Sh. Mesroghli, S. Chehreh Chelgani
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引用次数: 29

Abstract

The assay and recovery of rare earth elements (REEs) in the leaching process is being determined using expensive analytical methods: inductively coupled plasma atomic emission spectroscopy (ICP-AES) and inductively coupled plasma mass spectroscopy (ICP-MS). A neural network model to predict the effects of operational variables on the lanthanum, cerium, yttrium, and neodymium recovery in the leaching of apatite concentrate is presented in this article. The effects of leaching time (10 to 40 min), pulp densities (30% to 50%), acid concentrations (20% to 60%), and agitation rates (100 to 200 r/min), were investigated and optimized on the recovery of REEs in the laboratory at a leaching temperature of 60°C. The obtained data in the laboratory optimization process were used for training and testing the neural network. The feed-forward artificial neural network with a 4-5-5-1 arrangement was capable of estimating the leaching recovery of REEs. The neural network predicted values were in good agreement with the experimental results. The correlations of R=1 in training stages, and R=0.971, 0.952, 0.985, and 0.98 in testing stages were a result of Ce, Nd, La, and Y recovery prediction respectively, and these values were usually acceptable. It was shown that the proposed neural network model accurately reproduced all the effects of the operation variables, and could be used in the simulation of a leaching plant for REEs.

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应用人工神经网络预测磷灰石精矿中钇、镧、铈和钕的浸出回收率
在浸出过程中,稀土元素的测定和回收正在使用昂贵的分析方法:电感耦合等离子体原子发射光谱(ICP-AES)和电感耦合等离子体质谱(ICP-MS)。本文提出了一种预测操作变量对磷灰石精矿浸出过程中镧、铈、钇和钕回收率影响的神经网络模型。在实验室条件下,研究了浸出时间(10 ~ 40 min)、矿浆浓度(30% ~ 50%)、酸浓度(20% ~ 60%)和搅拌速率(100 ~ 200 r/min)对稀土元素回收率的影响,并对浸出温度为60℃进行了优化。将实验室优化过程中获得的数据用于神经网络的训练和测试。采用4-5-5-1排布的前馈人工神经网络能够估计稀土的浸出回收率。神经网络预测值与实验结果吻合较好。Ce、Nd、La、Y的回收率预测结果,训练阶段R=1,测试阶段R=0.971、0.952、0.985、0.98的相关系数均为可接受值。结果表明,所建立的神经网络模型能准确地再现操作变量的所有影响,可用于稀土浸出厂的模拟。
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