Heat transfer in the plastic phases I and II of cyclopentane

Abstract

Thermal conductivity of solid cyclopentane C5H10 has been measured at isochoric conditions in the plastic phases I and II for samples of different densities. Isochoric thermal conductivity is nearly constant in phase II and increases with temperature in phase I. Such behaviour is attributed to weakening of the translational orientational coupling which, in turn, leads to a decrease of phonon scattering on rotational excitations. The experimental data are described in terms of a modified Debye model of thermal conductivity with allowance for heat transfer by both low-frequency phonons and diffusive modes.