Study of the Thermodynamic Quantities of Adsorption and Activation of Piroxicam in Copper Corrosion in a Nitric Acid Environment

A. Ehouman, Yao Valery Kouadio, Mariko Kalifa, Amara Bamba, A. Kouakou, K. Bamba, P. Niamien, Benjamin Yao
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Abstract

The objective of this work is to assess the inhibitory efficacy of the piroxicam molecule on copper corrosion in a 1M nitric acid medium using the mass loss technique (gravimetry). The inhibition efficiency, represented as IE (%), increases with higher concentrations and temperatures. Various adsorption isotherm models (Langmuir, El-Awady, Freundlich, and Temkin) were employed to describe the interactions between the molecule and metallic copper. The Dubinin-Radushkevich isotherm, along with the Adejo-Ekwenchi isotherm, was utilized to identify the types of adsorption. Additionally, the thermodynamic adsorption and activation functions were determined and analyzed.
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硝酸环境下吡罗昔康在铜腐蚀中吸附和活化的热力学量研究
这项工作的目的是利用失重技术(重量法)评估吡罗昔康分子在1M硝酸介质中对铜腐蚀的抑制效果。抑菌效率,用IE(%)表示,随着浓度和温度的升高而增加。采用不同的吸附等温线模型(Langmuir, El-Awady, Freundlich和Temkin)来描述分子与金属铜之间的相互作用。利用Dubinin-Radushkevich等温线和Adejo-Ekwenchi等温线来确定吸附类型。此外,测定并分析了其热力学吸附和活化功能。
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