INCREASING WATER RESISTANCE OF WOOD WITH IMPREGNANT COMPOSITION BASED ON VEGETABLE OIL WITH SILICON DIOXIDE NANOPOWDER

E. Tomina, A. Dmitrenkov, Konstantin Zhuzhukin, N. Khodosova, N. Mozgovoy
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Abstract

The aim of the work was to develop and study new compositions for the treatment of natural wood based on used vegetable oil with the addition of nanosized silicon oxide to obtain a wood composite with improved properties. Specimens of birch wood were chosen as objects of the study. The basis of the developed impregnating compositions was used frying vegetable oil. The compositions were supplemented with additives of amorphous and crystalline silicon oxide nanopowders at a dosage of 0.01 to 0.5%. To modify wood, a stable suspension of synthesized silicon oxide nanopowders in used sunflower oil was prepared. The processing of wood specimens was carried out by the method of "hot-cold impregnation". The obtained wood composites with the addition of nanosized silicon oxide had improved hydrophobic properties of wood (an increase in the contact angle by 30%), increased moisture and water resistance (by 11 and 14 times, respectively), as well as reduced swelling in the tangential (by 4 times) and radial (5 times) directions in comparison with natural wood after 1 day of testing. The optimal dosage of silicon oxide nanopowders (0.01%) was chosen. A comparative evaluation of the use of amorphous and crystalline silicon oxides in impregnating compositions based on used vegetable oil was carried out using birch wood as an example. Impregnation compositions based on waste vegetable oil have low toxicity and their use makes it possible to dispose of production waste
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植物油与二氧化硅纳米粉浸渍组合物提高木材的耐水性
这项工作的目的是开发和研究新的组合物,用于处理以废植物油为基础的天然木材,并添加纳米级氧化硅,以获得具有改进性能的木材复合材料。选择桦木标本作为研究对象。所研制的浸渍剂以煎炸植物油为基础。在所述组合物中添加添加量为0.01 ~ 0.5%的非晶和晶体氧化硅纳米粉。为了对木材进行改性,在废葵花籽油中制备了合成氧化硅纳米粉的稳定悬浮液。木材试样的加工采用“冷热浸渍法”进行。经过1天的测试,添加纳米氧化硅的木材复合材料的疏水性(接触角增加30%),防潮性和耐水性分别提高了11倍和14倍,并且在切向(4倍)和径向(5倍)方向上减少了膨胀。选择了氧化硅纳米粉的最佳用量(0.01%)。以桦木为例,对非晶硅氧化物和结晶硅氧化物在废植物油浸渍组合物中的应用进行了对比评价。以废植物油为基础的浸渍组合物具有低毒性,其使用使处理生产废弃物成为可能
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