A Review on Integrated Mineral Carbonation Process in Ultramafic Mine Deposit

Abstract

Dramatical increase in the CO 2 concentration in the atmosphere has led to the climate change, which poses a significant threat to human life on Earth. CO 2 sequestration via mineral carbonation is the one of the most effective method for mitigating global warming, and is the only way that could store CO 2 permanently. In recent years, integrating mineral carbonation via ultramafic mine deposit has received significant attention due to its high potentiality towards commercial application. This review compiles the work conducted by various researchers over the last few years on integrated mineral carbonation processes in mining industry, which use the mine waste materials as CO 2 feedstock for mineral carbonation. This paper initially introduces the basic theory of mineral carbonation, with a brief description of various techniques that enhance the rate of mineral carbonation. The enhanced mineral carbonation strategies include pre-treatment of feedstock by thermal, chemical and mechanical activation, and carbonation in a direct or indirect carbonation routes under gas/solid phase or aqueous phase. This paper then introduces the scope of application of integrated mineral carbonation. This includes the types of mine suitable for integrated mineral carbonation, the properties of mine waste materials preferable for CO 2 sequestration, and the worldwide locations potentially viable for integrated mineral carbonation. Moreover, this paper critically reviews and discusses the integrated mineral carbonation process in mining industry. The integrated mineral carbonation processes include modified passive carbonation techniques at tailing dams, and ex-situ carbonation routes using fresh tailings. The focus of the discussions is the role of reaction condition on the carbonation efficiency of mine waste with various mineralogy, and the drawback of each integrated mineral carbonation process. All the discussions lead to the suggestions on the technology improvement in the integrated mineral carbonation process. Finally, this paper reviews the economical assessments on the existing integrated mineral carbonation process. Literature to date indicates that the value-add by-products (i.e. recovered metals, valuable carbonated products) play an important role in commercialization of an integrated mineral carbonation process.