Characteristics of Organic El Device Using A Pppma Blue Light Emitting Polymer Doped with Fluorescent Dyes

IF 0.7 4区 化学 Q4 CHEMISTRY, MULTIDISCIPLINARY Molecular Crystals and Liquid Crystals Pub Date : 2004-01-01 DOI:10.1080/15421400490506018
S. Oh, J. Ham, C. Lee, H. Oh
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Abstract

We have synthesized a novel blue light emitting poly(N-(p-perylene)phenylmethacrylamide)(PPPMA)polymer having a perylene moiety in the side chain. The prepared polymer was very soluble in most organic solvents such as monochlorobenzene, THF, chloroform and benzene. A single-layered organic electroluminescence(EL)device consisting of ITO/PPPMA polymer + fluorescent dye dopants(DCM or Coumarin 6)/Al was fabricated, and then the effect of dye doping on the EL characteristics was examined. The luminescence of the doped devices was significantly influenced by the amount and structure of fluorescent dye molecules. The EL devices emitted red light(597 nm)and green light(558 nm)corresponding to the fluorescent dye molecules. Especially, EL device containing a DCM of 3 wt%emitted a red light with the high brightness of 600 cd/m2at a DC 15 V.
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掺杂荧光染料的Pppma蓝光发光聚合物有机El器件特性研究
我们合成了一种具有侧链苝基团的新型蓝光发光聚(N-(对苝)苯基甲基丙烯酰胺)(PPPMA)聚合物。该聚合物可溶于一氯苯、四氢呋喃、氯仿和苯等有机溶剂。制备了ITO/PPPMA聚合物+荧光染料掺杂剂(DCM或香豆素6)/Al组成的单层有机电致发光器件,考察了染料掺杂对器件电致发光特性的影响。荧光染料分子的数量和结构对掺杂器件的发光有显著影响。EL器件发出与荧光染料分子相对应的红光(597 nm)和绿光(558 nm)。特别是含有3wt % DCM的EL器件,在直流电压15v下发出600 cd/m2的高亮度红光。
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来源期刊
CiteScore
1.20
自引率
14.30%
发文量
248
审稿时长
2 months
期刊介绍: Established in 1966, Molecular Crystals and Liquid Crystals is a world-leading journal publishing original research papers in both an experimental and theoretical nature in three areas of specialization: liquid crystals, molecular crystals, and low-dimensional solids. These cover, but are not limited to: Liquid Crystals: -Electro- and magneto-optical phenomena; thermodynamics; phase transitions; structure; NMR and orientation-controlled spectroscopy; theory. Molecular Crystals: -Spectroscopy; energy and charge transfer; solid state reactions; photo and radiation effects Low-dimensional Solids: -Structure, electronic, magnetic, and optical properties; transport mechanisms The journal publishes research papers, review papers, and book reviews. In all three areas, experimental manuscripts describing both preparation and properties will be considered. Papers that describe determination of crystal structure alone are not encouraged unless some solid state forces (hydrogen bonding, charge transfer, etc.) are playing a significant role and/or some solid state properties of the materials are measured.
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