{"title":"Organoaluminum Compounds and Lewis Pairs","authors":"M. Layh, W. Uhl, G. Bouhadir, D. Bourissou","doi":"10.1002/9780470682531.PAT0839","DOIUrl":null,"url":null,"abstract":"This chapter is dedicated to bifunctional derivatives associating Al with P- or N-containing Lewis bases. The synthesis and structure of these Lewis pairs/ambiphilic derivatives are described (presence or not of P/N Al interactions). Both unimolecular and bimolecular compounds are considered. Their reactivity towards small molecules (CO2, alkene, alkynes, isocyanides, amine-boranes, BX3, hydrides, and so on) including catalytic transformations are then presented. The synthesis and reactivity of transition metal complexes deriving from Al/P ambiphilic ligands are also presented. Whenever possible, the Al-compounds are compared to their lighter B congeners. \n \n \nKeywords: \n \nσ-acceptor; \nactivation; \nambiphilic; \naluminum; \nbifunctional; \ncatalysis; \nfrustrated Lewis pairs; \nM Al interactions; \nLewis acids; \nligands; \nphosphines; \nsmall molecules","PeriodicalId":20036,"journal":{"name":"Patai's Chemistry of Functional Groups","volume":"10 1","pages":"1-46"},"PeriodicalIF":0.0000,"publicationDate":"2016-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Patai's Chemistry of Functional Groups","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1002/9780470682531.PAT0839","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 5
Abstract
This chapter is dedicated to bifunctional derivatives associating Al with P- or N-containing Lewis bases. The synthesis and structure of these Lewis pairs/ambiphilic derivatives are described (presence or not of P/N Al interactions). Both unimolecular and bimolecular compounds are considered. Their reactivity towards small molecules (CO2, alkene, alkynes, isocyanides, amine-boranes, BX3, hydrides, and so on) including catalytic transformations are then presented. The synthesis and reactivity of transition metal complexes deriving from Al/P ambiphilic ligands are also presented. Whenever possible, the Al-compounds are compared to their lighter B congeners.
Keywords:
σ-acceptor;
activation;
ambiphilic;
aluminum;
bifunctional;
catalysis;
frustrated Lewis pairs;
M Al interactions;
Lewis acids;
ligands;
phosphines;
small molecules
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
