Treatment of Contaminated Textile Factories’ Wastewater by Photocatalyst Degradation

A. K. Hassan, A.F. Hassan, A. Jasim, Salam Naser Owaiyd
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Abstract

The aim of this work is remove the textile factories’ wastewater such as dyes via the Advanced Oxidation Processes (AOPs) that on using the nano titanium dioxide photocatalytic degradation. The degradation of C. I. Reactive black 45 (RB 45) in aqueous medium by the photocatalysis process has been studied. The effects of several parameters such as pH, the concentration of TiO2, irradiation time, and dye concentration have been examined. The optimal parameters were found to be [TiO2] = 0.75 g/L, irradiation time 480 min and pH=3.0. The results shown that the photocatalytic degradation could be enhanced by adding hydrogen peroxide H2O2 or potassium persulfate K2S2O8, for example, the efficiency increased from 68.9% to 88.7% and 95.4% when added 0.027 M or 1.5 g/L of H2O2 and K2S2O8 respectively. Also, the effects of inorganic salts Na2SO4, Na2CO3, and NaCl on the degradation efficiency of the photocatalysis process were investigated.
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光触媒降解法处理受污染纺织厂废水
本研究的目的是利用纳米二氧化钛光催化降解的高级氧化工艺(AOPs)去除纺织厂的染料等废水。研究了光催化降解水中c.i.活性黑45 (rb45)的工艺。考察了pH、TiO2浓度、辐照时间、染料浓度等参数对合成效果的影响。最佳工艺参数为[TiO2] = 0.75 g/L,辐照时间480 min, pH=3.0。结果表明,加入过氧化氢H2O2或过硫酸钾K2S2O8均能提高光催化降解效率,分别加入0.027 M和1.5 g/L的H2O2和K2S2O8时,光催化降解效率由68.9%提高到88.7%和95.4%。同时,考察了Na2SO4、Na2CO3和NaCl等无机盐对光催化降解效率的影响。
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