Photocatalytic Degradation of Reactive Yellow Dye in Wastewater using H2O2/TiO2/UV Technique

Q4 Chemical Engineering Journal of Chemical and Petroleum Engineering Pub Date : 2020-03-29 DOI:10.31699/ijcpe.2020.1.3
N. Mohammed, Abeer I. Alwared, M. Salman
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引用次数: 12

Abstract

In the present study, advanced oxidation treatment, the TiO2 /UV/H2O2  process was applied to decolorisation of the reactive yellow dyes in aqueous solution. The UV radiation was carried out with a 6 W low-pressure mercury lamp. The rate of color removal was studied by measuring the absorbency at a characteristic wavelength. The effects of H2O2 dosage, dye initial concentration and pH on decolorisation kinetics in the batch photoreactor were investigated. The highest decolorisation rates were observed (98.8) at pH range between 3 and 7. The optimal levels of H2O2 needed for the process were examined. It appears that high levels of H2O2 could reduce decolorisation by scavenging the *OH. The color degradation rate decreases as the dye concentration increases. The rate coefficient (k=0.0319 min-1) of degradation, follows the pseudo-first-order kinetics.
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H2O2/TiO2/UV光催化降解废水中活性黄色染料
本研究采用TiO2 /UV/H2O2工艺对活性黄色染料进行深度氧化脱色。紫外线辐射是用6w低压汞灯进行的。通过测量特征波长处的吸光度,研究了去色率。考察了H2O2投加量、染料初始浓度和pH对间歇光反应器脱色动力学的影响。pH值为3 ~ 7时,脱色率最高(98.8)。考察了该工艺所需的最佳H2O2浓度。高水平的H2O2似乎可以通过清除*OH来减少脱色。随着染料浓度的增加,颜色降解率降低。降解速率系数k=0.0319 min-1,符合准一级动力学。
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1.20
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审稿时长
8 weeks
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