{"title":"Lead tetra-acetate oxidation of NN-dimethylglycine and its relevance to the biosynthesis of the pyrrolidine ring of nicotine","authors":"E. Leete","doi":"10.1039/C29710001524","DOIUrl":null,"url":null,"abstract":"A degradative sequence which has been used to determine the distribution of radioactivity in the pyrrolidine of nicotine involves, as one of the steps, the oxidation of NN-dimethylglycine with lead tetra-acetate; the formaldehyde produced in this reaction, formerly thought to originate entirely from C-2, has been shown to be derived in appreciable amounts from the N-methyl groups.","PeriodicalId":17278,"journal":{"name":"Journal of The Chemical Society D: Chemical Communications","volume":"72 1","pages":"1524-1525"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of The Chemical Society D: Chemical Communications","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/C29710001524","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
Abstract
A degradative sequence which has been used to determine the distribution of radioactivity in the pyrrolidine of nicotine involves, as one of the steps, the oxidation of NN-dimethylglycine with lead tetra-acetate; the formaldehyde produced in this reaction, formerly thought to originate entirely from C-2, has been shown to be derived in appreciable amounts from the N-methyl groups.
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