{"title":"Polymerization and copolymerization of metal-containing monomers as a means of preparing immobilized catalysts","authors":"A.D. Pomogailo","doi":"10.1016/0167-6989(88)90056-6","DOIUrl":null,"url":null,"abstract":"<div><p>Conditions for preparing polymer-supported metal complex catalysts by polymerization and copolymerization of metal-containing monomers (MCM), i.e., compounds with a metal-containing unit and a multiple bond capable of polymerization, were analysed. Three main types of MCM, their composition and structure, and peculiarities of their homo- and copolymerization are described. The main conversions different from polymerization of conventional monomers are highlighted. The structural arrangement of both the metal complexes and the MCM-based polymers are considered, as well as the conversion observed upon incorporation in the macrochain. The main directions of application of MCM and MCM-based polymers in catalysis are defined.</p></div>","PeriodicalId":101060,"journal":{"name":"Reactive Polymers, Ion Exchangers, Sorbents","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1988-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0167-6989(88)90056-6","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reactive Polymers, Ion Exchangers, Sorbents","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0167698988900566","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
Conditions for preparing polymer-supported metal complex catalysts by polymerization and copolymerization of metal-containing monomers (MCM), i.e., compounds with a metal-containing unit and a multiple bond capable of polymerization, were analysed. Three main types of MCM, their composition and structure, and peculiarities of their homo- and copolymerization are described. The main conversions different from polymerization of conventional monomers are highlighted. The structural arrangement of both the metal complexes and the MCM-based polymers are considered, as well as the conversion observed upon incorporation in the macrochain. The main directions of application of MCM and MCM-based polymers in catalysis are defined.
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