Effects of erosion on corrosion of type 430 and 316 stainless steels in aqueous environments

X. Zhao, N. Cui, J. Luo, S. Chiovelli
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引用次数: 4

Abstract

Abstract The effects of erosion on the corrosion of two types of stainless steel in aqueous 0·5M NaCl and 1M NaCl environments at ambient temperature have been studied using a modified rotating cylinder electrode system. Erosion by silica particles greatly increased the passive current density for both ferritic type 430 and austenitic type 316 stainless steels. It is suggested that two factors were largely responsible for the observed effects. The impact of the eroding silica particles on the specimen surface destroyed the passive film and removed corrosion products from the specimen surface; and impact with the fast moving silica particles generated numerous microplastic deformation sites on the metal surface which were activated owing to the presence of residual stress, dislocations and defects, etc., and the emission of low energy electrons.
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冲蚀对430型和316型不锈钢在水环境中的腐蚀影响
摘要采用改进的旋转圆柱电极系统,研究了冲蚀对两种不锈钢在0·5M NaCl和1M NaCl水溶液中常温腐蚀的影响。对于铁素体430型和奥氏体316型不锈钢,二氧化硅颗粒的侵蚀大大增加了无源电流密度。有人认为,两个因素在很大程度上造成了观察到的影响。侵蚀二氧化硅颗粒对试样表面的冲击破坏了钝化膜,将腐蚀产物从试样表面去除;与快速移动的二氧化硅颗粒的碰撞在金属表面产生了许多微塑性变形位点,这些变形位点由于残余应力、位错和缺陷等的存在以及低能电子的发射而被激活。
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