Synthesis and Characterization of New Schiff Base and Its Metal (Cu, Ni, Co, Zn, Mn) Complexes

I. Yıldırım, M. Şekerci, M. Karatepe
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Abstract

Many chemists have reported on the chemical, structural and biological properties of Schiff bases. In this study, ([(2hydroxybenzylidene)-3methylurea]) Schiff base derivative and ıts metal (Cu, Co, Ni, Mn, Zn) complexes have been synthesized and characterized. From the elemental analyses date we found that the complexes have general formula [Mn](L)2], [Co](L)2].H2O, [Zn](L)2].3H2O, [Cu](L)2].4H2O, [Ni](L)2].2H2O. From the magnetic moment and UV-Vis spectral studies, the geometrical shape for the complexes of Mn (II), Co (II) and Zn (II) are octahedral, for the complexes of Ni (II) it is tetrahedral. While it is square-planar for the complexes of Cu (II).
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新型席夫碱及其金属(Cu, Ni, Co, Zn, Mn)配合物的合成与表征
许多化学家已经报道了希夫碱的化学、结构和生物学性质。本研究合成了([(2 -羟基苄基)-3甲基脲])希夫碱衍生物和ıts金属(Cu, Co, Ni, Mn, Zn)配合物并对其进行了表征。从元素分析数据中我们发现配合物具有通式[Mn](L)2], [Co](L)2]。水,(锌)(L) 2]。3 h2o(铜)(L) 2]。4水,(Ni) (L) 2) .2H2O。从磁矩和紫外可见光谱研究来看,Mn (II)、Co (II)和Zn (II)配合物的几何形状为八面体,Ni (II)配合物的几何形状为四面体。而Cu (II)配合物为方平面。
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