"Blending of Acrylic Superplasticizer with Napthalene, Melamine or Lignosulfoate-Based Polymers"

L. Coppola, E. Erali, R. Troli, M. Collepardi
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引用次数: 5

Abstract

Acrylic polymer (AP) performs better than other superplasticizers based on sulfonate-naphthalene-formaldehyde (SNF), sulfonated-melamine formaldehyde (SMF) or modified lignosulfonate (MLS). It is better than the other superplasticizers in terms of higher initial slump, at equal water-cement ratio (w/c), and lower rate of slump loss. AP, however, is a little more expensive than SMF and much more expensive than either NSF or MLS. Therefore, blending of AP with the other polymers could reduce the cost. The purpose of the present work was to study the influence of binary blended admixture (AP on one hand, and SNF, MSF or MLS on the other one) on the performance of superplasticized concretes in terms of slump, slump loss, specific gravity, air content and compressive strength at equal w/c. The data presented in this paper indicates that there is no practical advantage in blending AP with NSF or MSF. Moreover the combination of AP with NSF seems to be unreliable because produces an erratic reduction in the workability of the concrete mixture when about 75% of AP is replaced by NSF. On the other hand, a combination of AP with MLS appears to perform as well as the pure acrylic polymer in terms of workability, slump loss, air content and strength development, provided that the replacement of AP by MLS is not higher than 25%. Therefore, these blended AP-MLS superplasticizers appear to be very interesting because they are cheaper than the pure acrylic polymer at approximately equal performance.
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丙烯酸高效减水剂与萘、三聚氰胺或木质素磺酸基聚合物的共混
丙烯酸聚合物(AP)性能优于其他基于磺化萘甲醛(SNF)、磺化三聚氰胺甲醛(SMF)或改性木质素磺酸盐(MLS)的高效减水剂。在相同水灰比(w/c)下,其初始坍落度较高,坍落度损失率较低,均优于其他高效减水剂。然而,AP比SMF贵一点,比NSF或MLS贵得多。因此,AP与其他聚合物共混可以降低成本。本研究的目的是研究二元掺合料(AP, SNF, MSF或MLS)在等w/c条件下对超塑混凝土坍落度、坍落度损失、比重、空气含量和抗压强度的影响。本文提供的数据表明,AP与NSF或MSF混合没有实际优势。此外,AP与NSF的组合似乎是不可靠的,因为当约75%的AP被NSF取代时,混凝土混合物的和易性会产生不稳定的降低。另一方面,在MLS替代AP不高于25%的条件下,AP与MLS的组合在和易性、坍落度损失、空气含量和强度发展方面表现得与纯丙烯酸聚合物一样好。因此,这些混合AP-MLS高效减水剂看起来非常有趣,因为它们比纯丙烯酸聚合物便宜,性能大致相同。
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