Tetrakis(triphenylphosphine)palladium(0)

Abstract

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Keywords: preparation; hexamethyl-trans-σ-trishomobenzene (2); preparation; olefins from vinyl halides and alkyllithiums; beckmann fragmentation of ketoximes; aryl- and vinyl-substituted acetylenes; dehydrobromination of α-bromo ketones; ketone synthesis; extrusion of mercury from bis(propenyl)mercury; allylation of amines; alkenes from vinyl iodides and grignard reagents; conjugated enynes; arylalkynes; unsymmetrical biaryls and diarylmethanes; vinyl nitriles; cyclization via π-allylpalladium complexes; steroid side chain; cyclization to medium-sized lactones; chiral methyl chiral lactic acid (5); isomerization of 1,3-diene epoxides; alkylation of vinyl lactones; reductive acylation of alkoxy-substituted allylic acetates; methylenecyclopentanes; stereospecific synthesis of alkenes; cross-coupling of aryl halides and 1-alkenylboranes; iboga alkaloids; isomerization and elimination of allylic acetates; supported reagent; coupling of allyl bromides and allylstannanes; decarboxylation of β-acetoxy carboxylic acids; cleavage of endoperoxides; alkylation of dihydropyranyl acetates; alkylation and amination of allylic phosphates; 1,4-Dienes; α-Allylated ketones; alkylation of allyl nitroalkanes; allylation of nucleophiles; alkylation of vinyl epoxides; vinylsilanes; nucleophilic substitution reactions with α-acetoxy-β,γ-unsaturated nitriles; macrocyclization; macroheterocyclization; β-Keto esters; double silylation; allylic sulfones; 2,3-Disubstituted bicyclo[2.2.1]heptanes; desulfonylation; homoallylic alcohols; sequential π-allylpalladium alkylation; biaryls; 1,3-Dienes; heterosubstituted 1,3-dienes; 1,3-Diynes; allenynes; coupling of vinyl triflates with organotins; acylation of organozinc reagents; β-Carboline synthesis; allylation of potassium enoxyborates; allylic amination; macrocyclization by allylation–alkylation; steroidal 6β-hydroxy-2,4-diene-1-ones; trans-  cis-Cinnamic acids; RX  RCHO; coupling of vinyl triflates with alkenes; α-Diketones; carbonylation of 1-iodo-1,4- and -1,5-dienes; conjugate reduction; denitro-sulfonylation; allylic sulfones; coupling of 1-alkenylboranes with 1-bromoalkenes or -alkynes; cross-coupling of organoalanes with allylic acetals or ortho esters; carbonylation; 1,4-diazepines; decarbonylative cross coupling of acyl halides; decarbonylation of acyl cyanides; allylation of lithium 1-cyclopentenolates; asymmetric allylation; bisethynylation of vic-dichloroethylenes; pyrrolidines; piperidines; unsymmetrical biaryls; primary allylic amines; coupling of aryl triflates with organostannanes; coupling of vinylboranes and vinyl halides; intramolecular heck reactions; hydroxylamination; denitration of allylic nitro groups; coupling of RCOCl with Bu4Pb; intramolecular arylation; cyclizative heck coupling; [3 + 2]Annelation; Pd-catalyzed intramolecular ene reactions; allylidenation of aldehydes; 3-Aza-Cope rearrangement; biphenyls; coupling of alkylsilanes with aryl triflates; (Z,E)-2-Bromo-1,3-dienes; alkenyl sulfides; ArOTf+AlR3  ArR; 1,2-Diene-4-ynes; indole synthesis; sulfones; carbonylation of aryl and vinyl iodides; benzylpalladation; intramolecular heck cyclizations; intramolecular ene reactions; coupling of 1-alkynes and vinyl halides; coupling of 2-bromonaphthoquinones with stannanes; addition of (ArS)2 and (ArSe)2 to 1-alkynes; coupling of acid chloride with (E)-Bu3SnCH  CHSnBu3; 1,4-diketones; chiral oxazolines; stille carbonylative coupling; cyclization of triynes to benzenes; coupling of aryl iodides and arylboronic acids; allylic substitutions; allylation of carbonyl compounds and imines; coupling of organozincs with aryl halides; coupling of organozincs with alkenyl halides; coupling involving organoborons; coupling of organotins with unsaturated halides; destannylative acylation; coupling of organosilanes with aryl halides; cyclopropanation of norbornene; intramolecular zinc-ene reaction; deallylation; stille coupling; suzuki coupling; other cross-couplings; carbonylations; allylic substitutions; rearrangements; cycloadditions; hydrogenation; allyl and propargyl group transfer; suzuki coupling; intramolecular coupling of phenols with haloarenes; stille coupling; other reactions of organostannanes; negishi coupling; carbonylative coupling; arenes from enynes and diynes; cyclization; rearrangement; allylic displacements; tandem coupling and cyclization; cyclizations and cycloadditions; addition to alkynes; acylations; stille coupling; suzuki coupling; other coupling reactions; rearrangements; addition reactions; substitution reactions; coupling reactions; acylation and allylation; 2-pyridylpyrroles; coupling reactions; decarboxylative transformations; allylation; cyclizations; additions; cycloadditions; deprotection; coupling reactions; heterocycle synthesis; cleavage of C—O bonds; cyclization; cycloaddition; aminocarbonylation; addition; substitution; coupling reactions; isomerization; tetrabutylammonium fluoride, TBAF; tetrabutylammonium difluorotriphenylsilicate; tetracarbonylhydridorhenium; titanocene bis(triethyl phosphite); trimethylsilyl trifluoromethanesulfonate