{"title":"The interaction of UV-absorbers with hindered piperidines in photostabilization of cis-1,4-polybutadiene","authors":"Julia Lucki","doi":"10.1016/0144-2880(85)90011-9","DOIUrl":null,"url":null,"abstract":"<div><p>Interactions during the UV stabilization of <em>cis</em>-1,4-polybutadiene of a hindered piperidine (Tinuvin 770), its analogue hindered nitroxyl radical, 4-hydroxy-2,2,6,6-tetramethylpiperidino-1-oxy, with the UV-absorbers, ortho-hydroxybenzophenone and 2(2′-hydroxy-5-methylphenyl)benzotriazole (Tinuvin P) were investigated by using UV/VI, IR and ESR spectroscopy. Mechanisms for the observed antagonistic effects between the two groups of photostabilizers have been proposed.</p></div>","PeriodicalId":101036,"journal":{"name":"Polymer Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0144-2880(85)90011-9","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0144288085900119","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
Interactions during the UV stabilization of cis-1,4-polybutadiene of a hindered piperidine (Tinuvin 770), its analogue hindered nitroxyl radical, 4-hydroxy-2,2,6,6-tetramethylpiperidino-1-oxy, with the UV-absorbers, ortho-hydroxybenzophenone and 2(2′-hydroxy-5-methylphenyl)benzotriazole (Tinuvin P) were investigated by using UV/VI, IR and ESR spectroscopy. Mechanisms for the observed antagonistic effects between the two groups of photostabilizers have been proposed.