Statistical Treatments of Chloride Threshold and Corrosion Propagation Rate

C. Andrade, D. Izquierdo
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引用次数: 6

Abstract

The variability found in real structures is a function of the “intrinsic” variability of the material itself, of its aging with time and of the external climatic conditions, and, therefore, it is normal that the chloride threshold and the corrosion rates could vary spatially in the same structure or temporarily as the concrete ages. In present communication, some statistical distributions of chloride threshold are discussed, as well as the variability of the corrosion rate in real exposure conditions. In all both cases, the values found in laboratory specimens are in the same range than those found in real structures. The chloride threshold can vary from 0.2% to around 3% by weight of cement depending on the corrosion potential, which, in turn, depends on the particular condition of the steel bar in each structure. The corrosion rates show to be below 0.1 µA/cm2 when the steel is passive and values above 1 µA/cm2 are seldom found in real structures. The high variability when considering all choices may impact in a prediction of residual life of several decades of difference which aims into the need for the assessment of a specialized engineering judgement in function of the quality of the concrete and the exposure class.
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氯化物阈值与腐蚀扩展速率的统计处理
在实际结构中发现的可变性是材料本身的“内在”可变性的函数,它随时间的老化和外部气候条件,因此,氯离子阈值和腐蚀速率在同一结构中可能发生空间变化或随着混凝土老化而暂时变化是正常的。本文讨论了氯化物阈值的一些统计分布,以及实际暴露条件下腐蚀速率的变异性。在所有这两种情况下,在实验室标本中发现的值与在实际结构中发现的值在相同的范围内。根据腐蚀电位的不同,氯化物的阈值可以从水泥重量的0.2%到3%左右不等,而腐蚀电位又取决于每个结构中钢筋的特定条件。当钢处于钝化状态时,腐蚀速率低于0.1µA/cm2,在实际结构中很少发现高于1µA/cm2的腐蚀速率。在考虑所有选择时,高度可变性可能会影响几十年剩余寿命的预测差异,这就需要对混凝土质量和暴露等级的功能进行专门的工程判断评估。
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