PTFE Gasket Material Performance Variation With Thickness

Anita R. Bausman, Jeffer J. Wilson
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Abstract

Polytetrafluoroethylene (PTFE) is an excellent gasket material, chemically, but it has relatively poor mechanical performance. As a result, much effort has gone into improving the mechanical performance of PTFE-based gasket materials. Methods to improve mechanical performance include the addition of fillers (glass fibers, glass microspheres, silica, barium sulfate, carbon, etc.) and the manipulation of the microstructure (micro-cellular, expanded, restructured, etc.). These various forms of PTFE materials can have widely varying mechanical performance. PTFE materials that are chemically the same will have significantly different mechanical performance if the manufacturing process and microstructure are different. An example is the performance of amorphous, virgin PTFE sheet compared to fibrillated, expanded PTFE (ePTFE) sheet. The thickness of a gasket material is another structural difference that results in different mechanical performance. This paper explores the difference in the mechanical performance of two common filled PTFE (fPTFE) materials that end-users often consider functionally the same at several industrially important thicknesses. The gasket materials are both barium sulfate-filled, restructured PTFE sheet materials. The mechanical performance of each material is compared for three thicknesses using the Hot Blowout Thermal Cycling test (HOBTC, ASTM WK61856 Rev 10-9-2020). [1] The thicknesses are 0.79 mm (0.031 inch), 1.60 mm (0.063 inch), and 3.18 mm (0.125 inch). The authors selected these thicknesses for performance review because of their usage in the industry. The thinnest, 0.79 mm (0.031 inch), is commonly used for instrument service. Very little performance data is publicly available on this thickness. The medium thickness, 1.60 mm (0.063 inch), is most commonly used in piping flanges. The thickest reviewed for this paper, 3.18 mm (0.125 inch), is commonly used for pressure vessels but also shows up in piping. Leakage testing according to the Room Temperature Tightness test (ROTT or ASTM F2836 Standard Practice for Gasket Constants for Bolted Joint Design) [2] was performed on the thinner 0.79 mm (0.031 inch) materials. HOBTC and ROTT testing was performed on an amtec TEMES fl.ai1 test fixture over the latter half of 2021 at the authors’ company. This data will demonstrate to the end-user how different the mechanical behavior can be of the same gasket material differing only in how thick it is.
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聚四氟乙烯垫片材料性能随厚度的变化
聚四氟乙烯(PTFE)是一种化学性能优良的垫片材料,但其机械性能相对较差。因此,人们在改善聚四氟乙烯基垫片材料的机械性能方面付出了很大的努力。提高机械性能的方法包括添加填料(玻璃纤维、玻璃微球、二氧化硅、硫酸钡、碳等)和操纵微观结构(微孔、膨胀、重构等)。这些不同形式的聚四氟乙烯材料可以具有广泛不同的机械性能。化学性质相同的聚四氟乙烯材料,如果制造工艺和微观结构不同,其机械性能也会有显著差异。一个例子是无定形的,原始的聚四氟乙烯片材的性能与纤维化的,膨胀的聚四氟乙烯(ePTFE)片材的比较。衬垫材料的厚度是导致机械性能不同的另一个结构差异。本文探讨了两种常见填充聚四氟乙烯(fPTFE)材料的机械性能差异,最终用户通常认为在几个工业上重要的厚度上功能相同。垫片材料都是硫酸钡填充,重组聚四氟乙烯板材材料。使用热风吹出热循环测试(HOBTC, ASTM WK61856 Rev 10-9-2020)比较每种材料在三种厚度下的机械性能。[1]厚度分别为0.79毫米(0.031英寸)、1.60毫米(0.063英寸)和3.18毫米(0.125英寸)。作者选择这些厚度进行性能评估是因为它们在工业中的使用情况。最薄的0.79毫米(0.031英寸),通常用于仪表维修。关于这种厚度的公开性能数据很少。中等厚度,1.60毫米(0.063英寸),最常用于管道法兰。本文回顾的最厚材料为3.18毫米(0.125英寸),通常用于压力容器,但也出现在管道中。根据室温密封性试验(ROTT或ASTM F2836螺栓连接设计垫片常数标准规程)[2]对较薄的0.79 mm(0.031英寸)材料进行泄漏试验。HOBTC和ROTT测试于2021年下半年在amtec TEMES fl.ai1测试夹具上进行。这些数据将向最终用户证明,相同的垫片材料,仅在厚度上不同,其机械性能会有多大差异。
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