Removal of Heavy Metal Cations (Copper, Lead, Zinc) from Water Runoff by Calcium Silicate Hydrate: Effect of the Co-Ion and Competition of Ions in Ternary Mixtures

M. Brogat, S. Pontvianne, L. Sigot, C. Vallières
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Abstract

The sorption behavior of calcium silicate hydrate (CSH) with respect to lead, copper and zinc was studied to consider its application to remove metal from water runoff. A series of kinetics of removal and isotherms were undertaken with single metal and mixture solutions. The sorption occurred by ion exchange with calcium. Sorption kinetics were modelled using pseudo-second order model. The weight capacities of CSH were lead > copper >> zinc when studied separately. The co-ion associated to the metal ion is of importance on the removal capacities.
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水合硅酸钙去除径流中的重金属阳离子(铜、铅、锌):三元混合物中共离子和离子竞争的影响
研究了水合硅酸钙(CSH)对铅、铜和锌的吸附行为,以考虑其在水径流中金属去除中的应用。对单金属溶液和混合溶液进行了一系列的去除动力学和等温线研究。吸附是通过钙离子交换发生的。吸附动力学采用拟二阶模型。单独研究CSH的重量容量为铅>铜>锌。与金属离子相结合的离子对去除能力有重要影响。
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