{"title":"Chromium-catalyzed homolytic scission of organic peroxides with t-butyl hydroperoxide and its relation to benzylic oxidation","authors":"Jacques Muzart, Abdelaziz N'Ait Ajjou","doi":"10.1016/0304-5102(94)00068-9","DOIUrl":null,"url":null,"abstract":"<div><p>In using 9-(<em>t</em>-butylperoxy)-fluorene as test substrate and various chromium compounds, it has been shown that the transformation to fluorenone requires the simultaneous presence of <em>t</em>-BuOOH to be efficient. This transformation is much less effective when using free <em>t</em>-BuO<sup>.</sup> or <em>t</em>-BuOO<sup>.</sup> radicals. A mechanism involving the homolytic scission of the peroxidic bond of the substrate is proposed.</p></div>","PeriodicalId":16567,"journal":{"name":"分子催化","volume":"92 2","pages":"Pages 141-147"},"PeriodicalIF":0.0000,"publicationDate":"1994-08-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0304-5102(94)00068-9","citationCount":"18","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"分子催化","FirstCategoryId":"1089","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0304510294000689","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"Chemical Engineering","Score":null,"Total":0}
引用次数: 18
Abstract
In using 9-(t-butylperoxy)-fluorene as test substrate and various chromium compounds, it has been shown that the transformation to fluorenone requires the simultaneous presence of t-BuOOH to be efficient. This transformation is much less effective when using free t-BuO. or t-BuOO. radicals. A mechanism involving the homolytic scission of the peroxidic bond of the substrate is proposed.
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