Synthesis of high-quality ZnTe:Cu films as a back contact layer for CdTe solar cells

Xinlu Lin, Yufeng Zhang, Ziyao Zhu, Qiuchen Wu, Xiangxin Liu
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Abstract

P-type copper-doped zinc telluride (ZnTe:Cu) is a good candidate as a back contact of cadmium telluride (CdTe) solar cell. The deposition rate, transmittance and resistivity of ZnTe:Cu films deposited via target bias radio frequency (r.f.) sputtering was studied. The target bias voltage considerably influenced ZnTe:Cu film resistivity. In the meantime we find that post-deposition heat treatment (PDHT) significantly reduces the electrical resistivity of the ZnTe:Cu films, which is due to increases in both carrier concentration and mobility. It is inspiring for us to further improve the conductivity of ZnTe:Cu by applying the r.f. coupled d.c. sputtering and PDHT.
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高质量ZnTe:Cu薄膜作为CdTe太阳能电池背接触层的合成
p型铜掺杂碲化锌(ZnTe:Cu)是碲化镉(CdTe)太阳能电池背触点的良好候选材料。研究了靶偏置射频溅射法制备的ZnTe:Cu薄膜的沉积速率、透射率和电阻率。目标偏置电压对ZnTe:Cu薄膜的电阻率影响较大。同时,我们发现沉积后热处理(PDHT)显著降低了ZnTe:Cu薄膜的电阻率,这是由于载流子浓度和迁移率的增加。利用射频耦合直流溅射和PDHT进一步提高ZnTe:Cu的导电性对我们具有启发意义。
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