CdSe Quantum Dots and SBMA/CdSe Nanocomposites Characterization by Optical and 2D DOSY NMR Methods

I. Geru, O. Bordian, I. Culeac, V. Verlan
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引用次数: 1

Abstract

We present experimental results on preparation and characterization of colloidal CdSe quantum dots (QDs) and polymer nanocomposite based on them. CdSe QDs were characterized by UV absorbance and visible photoluminescence (PL) spectroscopy as well as 2D DOSY NMR. The average CdSe particles size estimated from the UV-Vis absorption spectra was found to be in good correlation with results obtained from NMR measurements. Nanocomposite thin films were prepared on the base of styrene with butylmethacrilate copolymer (SBMA) (1:1). CdSe QDs were successfully incorporated into the SBMA copolymer matrix and thin films of CdSe/SBMA nanocomposites were characterized by UV-Vis and PL spectroscopy.
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CdSe量子点和SBMA/CdSe纳米复合材料的光学和二维DOSY NMR表征
本文介绍了胶体CdSe量子点(QDs)的制备和表征及其聚合物纳米复合材料的实验结果。利用紫外吸收光谱、可见光致发光光谱以及二维DOSY NMR对CdSe量子点进行了表征。从紫外-可见吸收光谱估计的平均CdSe颗粒尺寸与核磁共振测量结果具有良好的相关性。以苯乙烯为基体,以甲基丙烯酸丁酯共聚物(SBMA)为共聚物(1:1)制备了纳米复合薄膜。将CdSe量子点成功地掺入SBMA共聚物基体中,并利用紫外可见光谱和PL光谱对CdSe/SBMA纳米复合材料薄膜进行了表征。
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