Removal of 2,6-dichloro-1,4-benzoquinone Precursors during Advanced Water Purification Process

IF 4.6 Q2 MATERIALS SCIENCE, BIOMATERIALS ACS Applied Bio Materials Pub Date : 2022-01-03 DOI:10.1080/01919512.2021.2014333
T. Nakai, K. Kosaka, M. Asami, M. Akiba
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Abstract

ABSTRACT The fates of 2,6-dichloro-1,4-benzoquinone (DCBQ) precursors were evaluated according to their formation potentials (FPs) upon chlorination during ozone/biological activated carbon treatment at two water purification plants (WPPs). DCBQ-FP levels in raw waters were 19 and 21 ng/L. DCBQ-FPs were slightly reduced by coagulation, sedimentation, and rapid filtration, but to < 8 ng/L by ozonation, in contrast to changes in absorbance at 260 nm and trihalomethane (THM)-FPs. DCBQ-FPs of water after sedimentation at WPP and secondary effluents at sewage treatment plants were decreased to a much greater extent than total THM-FPs at low ozone doses. Thus, ozonation is effective for removal of DCBQ precursors.
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高级水净化工艺中2,6-二氯-1,4-苯醌前体的去除
根据臭氧/生物活性炭处理过程中2,6-二氯-1,4-苯醌(DCBQ)前体在氯化作用下的形成势(FPs),对其命运进行了评价。原水DCBQ-FP含量分别为19和21 ng/L。经混凝、沉淀和快速过滤后,DCBQ-FPs略有降低,但经臭氧氧化后,DCBQ-FPs < 8 ng/L,与260 nm吸光度和三卤甲烷(THM)-FPs的变化相反。在低臭氧剂量下,WPP沉淀后的水和污水处理厂二次出水的DCBQ-FPs比总THM-FPs下降的幅度要大得多。因此,臭氧氧化对DCBQ前体的去除是有效的。
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来源期刊
ACS Applied Bio Materials
ACS Applied Bio Materials Chemistry-Chemistry (all)
CiteScore
9.40
自引率
2.10%
发文量
464
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