CO2 REMOVAL EFFICIENCY FROM NATURAL GAS AT ELEVATED PRESSURE OF PACKED ABSORPTION COLUMN USING POTASSIUM CARBONATE PROMOTED WITH GLYCINE

Nur Farhana Ajua Mustafa, A. M. Shariff, W. Tay, H. Halim, Siti Munirah Mhd Yusof
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引用次数: 2

Abstract

This article reports the absorption removal efficiency for carbon dioxide (CO2) capture from natural gas using an environmental friendly solvent, potassium carbonate promoted with glycine. Recently, CO2 capture using this solvent (with precipitating) was studied by previous researchers. However, the precipitates of the solvent increase the potential of blockage in the packing and piping thus result failure in absorption processes. Therefore, this study focused to assess the CO2 removal efficiency of non-precipitating potassium carbonate promoted with glycine. This green solvent contains aqueous blend of 20 wt% potassium carbonate and 8 wt% glycine. The absorption performance of the solvent was obtained by demonstrated a few experimental works using a bench scale packed absorption column. The packing type was Sulzer metal gauze and the column consisted of six sampling point which located equidistance along the packing The system was running over a range of liquid flow rate 1.81-7.22 m3/m2.h at fixed operating pressure (4 Mpa), CO2 inlet concentration (20%), gas flow rate (33 kmol/m2.h) and solvent temperature (60 . The effect of liquid flow rate was assessed in term of its CO2 removal efficiency and concentration profile along the packing. The study shows the increasing trend of CO2 removal as liquid flow rate increases. Higher liquid/molar flow rate gas (L/G) offers a better absorption performance compared to lower L/G ratio. This study demonstrated the efficient absorption up to 77 % using non-precipitating potassium carbonate promoted with glycine.
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甘氨酸促进碳酸钾填料吸收塔高压下天然气中Co2的脱除效率
本文报道了甘氨酸促进的环境友好型溶剂碳酸钾对天然气中二氧化碳的吸附脱除效果。近年来,前人研究了利用这种溶剂(带沉淀)捕获二氧化碳的方法。然而,溶剂的沉淀物增加了填料和管道堵塞的可能性,从而导致吸收过程失败。因此,本研究的重点是评估甘氨酸促进的非沉淀碳酸钾对CO2的去除效率。这种绿色溶剂含有20%碳酸钾和8%甘氨酸的水混合物。通过实验验证了该溶剂的吸附性能。填料类型为苏尔zer金属纱,柱由沿填料等距分布的6个采样点组成。系统在固定工作压力(4 Mpa)、CO2进口浓度(20%)、气体流速(33 kmol/m2.h)和溶剂温度(60 kmol/m2.h)下,在液体流量1.81 ~ 7.22 m3/m2.h范围内运行。考察了液体流量对填料CO2去除率和浓度分布的影响。研究表明,随着液体流量的增加,CO2去除率呈增加趋势。较高的液体/摩尔流量气体(L/G)比较低的L/G比具有更好的吸收性能。研究表明,甘氨酸促进的非沉淀碳酸钾吸收率高达77%。
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