라멜라 액정상 메이크업 클렌징 제형

여혜림, 이지현, 김수지, 노민주, 장지희, 김연준, 윤명석, 유권종, 이준배
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Abstract

This study is related to a lamellar liquid crystal make-up cleansing formulation with a hologram-like unique appearance between two polarizing plates. Make-up cleansing formulations with a lamellar liquid crystal phase have been extensively studied for a long time, but there have been limitations in practical commercialization because of increasing turbidity and viscosity. In this study, to solve this problem, alkyl chains of surfactants were modified to increase the fluidity of the liquid crystal phase, and electrostatic repulsion force was increased by introducing anionic surfactant. The lamellar liquid crystal make-up cleansing formulation which introduced anionic surfactants can easily inhibit crystallization through electrostatic repulsion force, thereby showing excellent stability overtime, maintaining transparent appearance and viscosity. In addition, we have newly introduced an in vitro cleansing evaluation method using fluorescent material and in vivo imaging system (IVIS) for objective and quantitative cleansing ability evaluation. The excellent cleansing ability of lamellar liquid crystal cleansing formulation has been confirmed by newly developed evaluation method. On the other hand, when lamellar liquid crystal make-up cleansing formulation was placed between orthogonally arranged two polarizing plates, a specific pattern like a hologram can be observed. This phenomenon is presumably interpreted as the interference between the visible light passing through the liquid crystal formulation and the lamellar structure. The lamellar structure of cleansing formulation was confirmed by SAXS analysis, exhibiting Bragg spacing ratio of 1 : 2. The lamellar liquid crystal make-up cleansing formulation prepared in this study would be useful for future application in make-up cleansing due to its excellent stability, cleansing ability, and unique hologram-like pattern placed between two polarizing plates.
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拉梅拉液晶化妆洁面乳型
本研究涉及一种在两个偏光片之间具有类似全息图的独特外观的层状液晶化妆清洁配方。长期以来,人们对层状液晶相的洗面奶配方进行了广泛的研究,但由于其浊度和粘度的增加,在实际商业化中受到了限制。为了解决这一问题,本研究通过对表面活性剂的烷基链进行改性来增加液晶相的流动性,并通过引入阴离子表面活性剂来增加静电斥力。引入阴离子表面活性剂的层状液晶彩妆清洁配方,容易通过静电斥力抑制结晶,从而长期表现出优异的稳定性,保持透明的外观和粘度。此外,我们还介绍了一种利用荧光材料和体内成像系统(IVIS)对体外清洁能力进行客观定量评价的方法。采用新开发的评价方法,证实了层状液晶清洁配方具有优异的清洁性能。另一方面,当层状液晶化妆清洁配方被放置在正交排列的两个偏振板之间时,可以观察到像全息图一样的特定图案。这种现象可以解释为通过液晶配方的可见光与层状结构之间的干涉。通过SAXS分析证实了清洁配方的层状结构,其Bragg间距比为1:2。本研究制备的层状液晶洗面奶配方具有优异的稳定性、清洁能力和独特的放置在两个偏振光片之间的全息图状图案,在未来的洗面奶中具有重要的应用价值。
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