S. R. Hosseinian, S. Fatemi, H. Hadadzadeh, M. Weil, A. D. Khalaji
{"title":"Synthesis and Crystal Structure of Bis(1,10-phenanthroline-5,6-dione)rhodium(I) Hexafluorophosphate, [Rh(phen-dione)2]PF6","authors":"S. R. Hosseinian, S. Fatemi, H. Hadadzadeh, M. Weil, A. D. Khalaji","doi":"10.2116/ANALSCIX.24.X287","DOIUrl":null,"url":null,"abstract":"The title compound, [Rh(phen-dione)2]PF6, where phen-dione is 1,10-phenanthroline-5,6-dione, crystallizes in the monoclinic space group P21/c (no. 14), with a = 9.5859(4)A, b = 17.6272(8)A, c = 13.5252(6)A, β = 91.025(1)°, V = 2285.02(17)A3, Z = 4, T = 100 K, R(F) = 0.0329, wR(F2) = 0.0894. The coordination polyhedron about the Rh(I) atom is a distorted [RhN4] bisphenoid with two independent phen-dione as ligands.","PeriodicalId":7796,"journal":{"name":"Analytical Sciences: X-ray Structure Analysis Online","volume":"79 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2008-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"3","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Analytical Sciences: X-ray Structure Analysis Online","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.2116/ANALSCIX.24.X287","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 3
Abstract
The title compound, [Rh(phen-dione)2]PF6, where phen-dione is 1,10-phenanthroline-5,6-dione, crystallizes in the monoclinic space group P21/c (no. 14), with a = 9.5859(4)A, b = 17.6272(8)A, c = 13.5252(6)A, β = 91.025(1)°, V = 2285.02(17)A3, Z = 4, T = 100 K, R(F) = 0.0329, wR(F2) = 0.0894. The coordination polyhedron about the Rh(I) atom is a distorted [RhN4] bisphenoid with two independent phen-dione as ligands.
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