{"title":"The electrochemical oxidation of anodic molybdenum into non-aqueous solutions of halogen","authors":"Jacob J. Habeeb, Colin Oldham, Dennis G. Tuck","doi":"10.1016/0022-1902(81)80554-4","DOIUrl":null,"url":null,"abstract":"<div><p>A molybdenum anode can be oxidised electrochemically into acetonitrile/X<sub>2</sub> media (X = Cl, Br, I), with current efficiencies which are lower than for the analogous chromium system. The subsequent work-up of solutions prepared by this method yields products containing molybdenum in either + II or + V oxidation states. A tentative reaction scheme is presented. Tungsten could not be oxidised electrochemically under the conditions used.</p></div>","PeriodicalId":16275,"journal":{"name":"Journal of Inorganic and Nuclear Chemistry","volume":"43 9","pages":"Pages 2087-2088"},"PeriodicalIF":0.0000,"publicationDate":"1981-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0022-1902(81)80554-4","citationCount":"4","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Inorganic and Nuclear Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0022190281805544","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 4
Abstract
A molybdenum anode can be oxidised electrochemically into acetonitrile/X2 media (X = Cl, Br, I), with current efficiencies which are lower than for the analogous chromium system. The subsequent work-up of solutions prepared by this method yields products containing molybdenum in either + II or + V oxidation states. A tentative reaction scheme is presented. Tungsten could not be oxidised electrochemically under the conditions used.
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