Application of Cellulose Acetate Reinforced Nanocomposite Fluorescence Film as Filter and Bio-Packaging Material with Antibacterial Properties

Y. Azeh, D. Adetitun, G. Olatunji, F. A. Adekola
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引用次数: 2

Abstract

Abstract In an effort at developing new filters and bio-packaging materials with antibacterial properties, nanocomposite fluorescence films of cellulose acetate reinforced with cellulose nanoparticles, methylcellulose nanoparticles, propylcellulose nanoparticles, toluene diisocyanate modified cellulose and cellulose acetate nanoparticles were prepared and characterized. The effects of the nanoparticles on the mechanical, crystallinity and morphology of the nanocomposite films was studied. The sensitivity of bacteria against the new nanocomposite films was experimented. Scanning electron microscopy showed the films to be well dispersed. Modulus increase was directly proportional to nanoparticle loading. Samples with maximum compatibility were cellulose nanoparticles (CNPs) loading of 40% with modulus of 113.3Mpa and toluene diisocyanate modified cellulose nanoparticles (TDI-CNPs) at 20% loading had 146.0Mpa. Others include cellulose acetate nanoparticles (CANPs) at 30% loading with 73.0Mpa; methylcellulose acetate nanoparticles (MCNPs) with 5% loading had a modulus of 87.3Mpa and pure cellulose acetate had 45.0Mpa. The films were applied as filters for the removal of cells of Bacillus; Enterococcus and Micrococcus sp. from the crude bacteriocin, with recoverability of 95.9% based on the bacteriocin produced. The films showed limited antibacterial properties against clinical Pseudomonas sp 1, Pseudomonas sp 2 and Proteus sp. It is concluded that the films showed limited antibacterial properties hence it has antibacterial potentials and capabilities.
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醋酸纤维素增强纳米复合荧光膜作为抗菌过滤和生物包装材料的应用
摘要为了开发具有抗菌性能的新型过滤器和生物包装材料,制备了纤维素纳米颗粒、甲基纤维素纳米颗粒、丙基纤维素纳米颗粒、甲苯二异氰酸酯改性纤维素和醋酸纤维素纳米颗粒增强的醋酸纤维素纳米复合荧光膜,并对其进行了表征。研究了纳米颗粒对纳米复合膜的力学性能、结晶度和形貌的影响。实验了细菌对新型纳米复合膜的敏感性。扫描电镜显示膜分散良好。模量的增加与纳米颗粒的载荷成正比。相容性最大的样品是负载40%的纤维素纳米粒子(CNPs),模量为113.3Mpa;负载20%的甲苯二异氰酸酯修饰的纤维素纳米粒子(TDI-CNPs),模量为146.0Mpa。其他包括30%负载、73.0Mpa的醋酸纤维素纳米颗粒(CANPs);负载5%的甲基乙酸纤维素纳米颗粒(MCNPs)的模量为87.3Mpa,纯醋酸纤维素的模量为45.0Mpa。用该膜作为滤膜去除芽孢杆菌;从粗细菌素中提取肠球菌和微球菌,回收率为95.9%。该膜对临床假单胞菌1、假单胞菌2和变形杆菌均表现出有限的抑菌性能,具有一定的抑菌潜力和抑菌能力。
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