Synthesis and Performance Research of Biodegradable Modified Polyaspartic Acid

Yu-hua Gao, Zhenfa Liu, Lihui Zhang, Yanji Wang
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引用次数: 9

Abstract

Modified polyaspartic acid (PASP-SEA-ASP) was prepared from polysuccinimide (PSI) that was thermal condensation polymer of aspartic acid (ASP), taurine (SEA) and ASP. The property of scale inhibition, dispersant and biodegradation of PASP-SEA-ASP were studied. The structure of modified polyaspartic acid was characterized by means of FTIR. Calcium carbonate crystals in scale samples were analysed by means of SEM. The results showed that under Ca2+ 400 mg/L, HCO3- 800 mg/L and PASP-SEA-ASP composite 4 mg/L, the scale inhibition rate of PASP-SEA-ASP was 67%. Under PASP-SEA-ASP composite 15 mg/L, the least diaphaneity of the top liquid on dispersing iron oxide was 53.8 %. And PASP-SEA-ASP possess better biodegradation performance and the highest biodegradation rate can reach 70%. Modified polyaspartic acid could distort calcium carbonate crystallite and made calcium carbonate crystallite more dispersive.
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可生物降解改性聚天冬氨酸的合成及性能研究
以天冬氨酸(ASP)、牛磺酸(SEA)和ASP的热缩合聚合物聚琥珀酰亚胺(PSI)为原料,制备了改性聚天冬氨酸(PASP-SEA-ASP)。研究了PASP-SEA-ASP的阻垢、分散剂和生物降解性能。用红外光谱对改性聚天冬氨酸的结构进行了表征。用扫描电子显微镜对水垢样中的碳酸钙晶体进行了分析。结果表明,在Ca2+ 400 mg/L、HCO3- 800 mg/L和PASP-SEA-ASP复合4 mg/L条件下,PASP-SEA-ASP的阻垢率为67%。在PASP-SEA-ASP复合物浓度为15 mg/L时,分散氧化铁的上液透明度最低为53.8%。PASP-SEA-ASP具有较好的生物降解性能,最高生物降解率可达70%。改性聚天冬氨酸能使碳酸钙晶体变形,使碳酸钙晶体更加分散。
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