Dielectric properties of nanocrystalline cellulose–potassium iodide composites

Aleksey Yu. Milinskiy
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Abstract

The linear and nonlinear dielectric properties of composites based on KIO3 and nanocrystalline Acetobacter Xylinum cellulose have been studied. This cellulose is structured so that it has a large amount of nano-channels with parallel arrangement and with diameters of 50–100 nm and the lengths being thousand-fold. The behavior of linear dielectric permittivity of bulk KIO3 was found to have four anomalies at the temperatures corresponding to phase transitions. The temperature elevations of 20 and 24 K, respectively, for the IV  III and III  II structural transitions were revealed for KIO3 in the pores of nanocrystalline cellulose relative to the corresponding transition temperatures in bulk KIO3. Possible causes for the revealed temperature elevations were discussed.

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纳米纤维素-碘化钾复合材料的介电性能
研究了KIO3与纳米醋酸杆菌木质素纤维素复合材料的线性和非线性介电性能。这种纤维素的结构使其具有大量平行排列的纳米通道,直径为50-100纳米,长度为千倍。在与相变相对应的温度下,块状KIO3的线性介电常数表现出四种异常。结果表明,纳米晶纤维素孔隙中KIO3的IV→III和III→II结构转变温度分别比块状KIO3的相应转变温度高20和24 K。讨论了显示温度升高的可能原因。
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