{"title":"Luminescent Metal-Organic Frameworks for Nitroaromatic Compounds Detection","authors":"Tianhao Zhao, Fenhang Zhang, Jing Zhou, Xiaoqing Zhao","doi":"10.1080/02603594.2020.1853537","DOIUrl":null,"url":null,"abstract":"ABSTRACT Luminescent metal-organic frameworks (LMOFs), as a subclass of MOFs, have attracted great attention, due to their promising potentials in practical applications. Therefore, as chemosensors, by combining the characteristic luminescent properties and the diversiform topological structures, LMOFs open up promising potentials for sensing. Nitroaromatic compounds (NACs) pose a great threat for environment and homeland security because of their toxicity and explosiveness, and then developing sensitive, selective, and reversible sensors for NACs is in great demand. In this review, we summarize recent works on LMOFs sensors for NACs through photophysical properties, sensing behaviors, possible mechanisms, existing problems and prospects for further developments. Graphical Abstract","PeriodicalId":10481,"journal":{"name":"Comments on Inorganic Chemistry","volume":"22 1","pages":"100 - 132"},"PeriodicalIF":3.8000,"publicationDate":"2020-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Comments on Inorganic Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1080/02603594.2020.1853537","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 2
Abstract
ABSTRACT Luminescent metal-organic frameworks (LMOFs), as a subclass of MOFs, have attracted great attention, due to their promising potentials in practical applications. Therefore, as chemosensors, by combining the characteristic luminescent properties and the diversiform topological structures, LMOFs open up promising potentials for sensing. Nitroaromatic compounds (NACs) pose a great threat for environment and homeland security because of their toxicity and explosiveness, and then developing sensitive, selective, and reversible sensors for NACs is in great demand. In this review, we summarize recent works on LMOFs sensors for NACs through photophysical properties, sensing behaviors, possible mechanisms, existing problems and prospects for further developments. Graphical Abstract
期刊介绍:
Comments on Inorganic Chemistry is intended as a vehicle for authoritatively written critical discussions of inorganic chemistry research. We publish focused articles of any length that critique or comment upon new concepts, or which introduce new interpretations or developments of long-standing concepts. “Comments” may contain critical discussions of previously published work, or original research that critiques existing concepts or introduces novel concepts.
Through the medium of “comments,” the Editors encourage authors in any area of inorganic chemistry - synthesis, structure, spectroscopy, kinetics and mechanisms, theory - to write about their interests in a manner that is both personal and pedagogical. Comments is an excellent platform for younger inorganic chemists whose research is not yet widely known to describe their work, and add to the spectrum of Comments’ author profiles, which includes many well-established inorganic chemists.