КИНЕТИКА КАТОДНОГО ВЫДЕЛЕНИЯ ВОДОРОДА НА МОНОСИЛИЦИДЕ МАРГАНЦА В СЕРНОКИСЛОМ ЭЛЕКТРОЛИТЕ

Abstract

Методами поляризационных и импедансных измерений изучена кинетика реакции выделения водорода на MnSi-электроде в сернокислых растворах с различной концентрацией ионов водорода. Сделано предположение о механизме выделения водорода на силициде. Отмечено влияние тонкой оксидной пленки на кинетику выделения водорода на MnSi при невысоких катодных поляризациях.       REFERENCES Rotinyan A. L., Tikhonov K. I., Shoshina I. A. Teoreticheskaya elektrokhimiya [Theoretical Electrochemistry]. Leningrad, Khimiya Publ., 1981, 424 p. (in Russ.) Antropov L. I. Teoreticheskaya elektrokhimiya [Theoretical Electrochemistry]. Мoscow, Vysshaya shkola Publ., 1984, 519 p. (in Russ.) Shamsul Huq A. K. M., Rosenberg A. J. J. Electrochemical behavior of nickel compounds. Electrochem. Soc. , 1964, v. 111(3), p. 270. https://doi.org/10.1149/1.2426107 Vijh A. K., Belanger G., Jacques R. Electrochemical reactions oh iron silicide surfaces in sulphuric acid. 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