Effect of Temperature and Salt Concentration on Rheological Behaviour of Surfactin

Abstract

Behavioural changes of surfactants due to temperature fluctuations, and its interaction with saline environment, is very common during oil and gas operations. Exhibition of transient or permanent flow behaviour is one form of these changes. Therefore, effect of temperature and ionic concentrations (salinity) on flow behaviour of sodium surfactin was experimentally investigated. ORCADA® software-controlled OFITE viscometer (Model 1100) was used to conduct steady-shear study, at 23–50 °C temperature, 0.1–1.5 molar (M) salt concentrations and 0.025–1.0 % surfactin dosages. Sodium surfactin behaves as non-Newtonian fluid, with a pseudoplastic pattern exhibited in aqueous and 0.25-1.5M saline media. Effect of changes in temperature and salinity on apparent viscosity of surfactin was surfactant-dosage dependent. Furthermore, shear-thickening effect set in at a critical shear rate of 680.9 s-1, signifying flow-induced self-aggregation. Surfactant dosages 0.075 and to a lesser extent 0.1% were minimally affected by changes in temperatures, salinity and rate of shear not exceeding 680.9 s-1. The findings suggest pumpability and dispersion characteristics of the biosurfactant.