{"title":"Gas Adsorption and Luminescent Properties of a Porous pcu-Type Zn(II) Coordination Polymer","authors":"Z. An, Jian Wang","doi":"10.1080/15533174.2015.1137061","DOIUrl":null,"url":null,"abstract":"A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"2","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2015.1137061","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 2
Abstract
A new Zn(II) compound, namely {Zn2(tdc)2(pi)}n (1 H2tdc = 2,5-thiophenedicarboxylic acid, pi = piperazine), has been synthesized via the solvothermal reactions of Zn(NO3)2·6H2O, H2tdc and pi. Single-crystal X-ray analysis reveals that compound 1 crystallizes in orthorhombic Pnma space group with cell parameters a = 20.734(6), b = 20.994(6), c = 18.539(6), and β = 90. The title compound features a three-dimensional (3D) pillar-layered framework. The gas adsorption and luminescent properties of 1 were investigated in the solid state at room temperature.
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