Adsorption of Aluminum, Arsenic and Sulphate Ions from Synthetic and Real Underground Water by Marine Fouling

S. A. El-Enein, Ahmed H. Mangoode, Fathy A. Elsayed, M. Hammad
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引用次数: 1

Abstract

The removal of Al3+, As3+ and SO42- ions from aqueous solution was investigated by using marine fouling. The effect of removal of adsorbent was studied in batch technique under various operating parameters such as pH, contact time, adsorbent dose, adsorbent particle size and metal ions concentration at 500 rpm and 25oC. The maximum removal of Al3+, As3+ and SO42- was 100% at pH 5 for Al3+, pH 8 for As3+ and pH 3 for SO42- using 0.7 g for 120 min. and 45 μm of adsorbent particle size. The Langmuir and Freundlich adsorption isotherm models were under taken to analyse the equilibrium data. Langmuir isotherm showed the best fit to the equilibrium data, which gave maximum adsorption capacity for Al3+, As3+ and SO42- was 28.81, 23.58 and 34.48 mg/g, respectively. The adsorption process follows the pseudo-second-order model. This study recommended that marine fouling can be used for removal of toxic metal ions due to highly efficiently and low cost.
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海洋污染对合成和真实地下水中铝、砷和硫酸盐离子的吸附研究
采用海洋污垢法研究了水中Al3+、As3+和SO42-离子的去除。在500rpm、25oC条件下,研究了不同操作参数(pH、接触时间、吸附剂剂量、吸附剂粒径、金属离子浓度)对吸附剂的去除效果。在Al3+的pH为5、As3+的pH为8和SO42-的pH为3时,吸附剂粒径为45 μm,用量为0.7 g,时间为120 min,对Al3+、As3+和SO42-的去除率达到100%。采用Langmuir和Freundlich吸附等温线模型对平衡数据进行了分析。Langmuir等温线最符合平衡数据,对Al3+、As3+和SO42-的最大吸附量分别为28.81、23.58和34.48 mg/g。吸附过程符合准二阶模型。研究结果表明,利用海洋污垢去除有毒金属离子具有高效、低成本的优点。
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