Migration of Plasticizers from Polyethylene Terephthalate Bottles to Vinegar and Water via different Temperature and Storage Periods

Seham Orabi, Taha A Abd-ElRazic, Hanaa H. Elsayed
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引用次数: 2

Abstract

lasticizers (diethyl phthalate (DEP), di-butyl phthalate (DBP), benzyl butyl phthalate (BBP), and diethyl hexyl phthalate (DEHP) are widely used in the manufacture of plastics. Phthalates are not covalently bound to the plastic matrix and can leach into food during packaging. This study investigated the migration of phthalate derivatives from Polyethylene terephthalate (PET) bottles into their water and vinegar under different storage conditions. Gas chromatography (GC) with a mass spectrometry (MS) system is used. The results showed that the highest migration level was DEHP levels after 4 months at 40ºC reached 62.5 and 51.9 µg/L in bottled water and vinegar these values were 10.4 and 8.65 times higher than the upper limit for maximum contamination level (MCL) in drinking water as regulated by U.S.EPA, which equal 6.0 µg/L for DEHP.
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增塑剂在不同温度和储存期下从聚对苯二甲酸乙二醇酯瓶向醋和水的迁移
塑化剂(邻苯二甲酸二乙酯(DEP)、邻苯二甲酸二丁酯(DBP)、邻苯二甲酸苄丁酯(BBP)和邻苯二甲酸二乙酯己酯(DEHP))广泛用于塑料制造。邻苯二甲酸酯不与塑料基体共价结合,可以在包装过程中渗入食品。研究了PET瓶中邻苯二甲酸酯衍生物在不同贮存条件下对水和醋的迁移。使用气相色谱(GC)和质谱(MS)系统。结果表明,在40℃条件下,瓶装水和食醋中DEHP在4个月后的迁移量最高,分别达到62.5µg/L和51.9µg/L,分别是美国环保署规定的饮用水中DEHP最高污染限量(MCL) 6.0µg/L的10.4和8.65倍。
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