{"title":"Ionothermal Synthesis, Crystal Structure, and Luminescent Properties of Two Novel Layered Indium-1,4-Benzenedicarboxylate Complexes","authors":"Saying Li, L. Du, Zhi-Hong Liu","doi":"10.1080/15533174.2014.989574","DOIUrl":null,"url":null,"abstract":"Two novel organic-inorganic hybrid indium complexes, [C6H11N2]2[In2(BDC)3Br2] (1) and [C7H13N2]2[In2(BDC) 3Br2] (2) (BDC2– = 1,4-benzenedicarboxylate), have been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, and TG. Single X-ray diffraction studies revealed that compounds 1 and 2 are isostructural. Both crystallize in the monoclinic system with space group P21/c. Their structures are characterized as novel graphite-like layered structure with larger rings constructed by InO5Br polyhedra and the 1,4-benzendicarboxylate organic linkers. The used ILs cations [C6H11N2]+ are located between the layers and compensate for the negative charges of framework. Furthermore, their luminescent properties have also been studied.","PeriodicalId":22118,"journal":{"name":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2016-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"1","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1080/15533174.2014.989574","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 1
Abstract
Two novel organic-inorganic hybrid indium complexes, [C6H11N2]2[In2(BDC)3Br2] (1) and [C7H13N2]2[In2(BDC) 3Br2] (2) (BDC2– = 1,4-benzenedicarboxylate), have been synthesized under ionothermal conditions and characterized by elemental analysis, FT-IR, and TG. Single X-ray diffraction studies revealed that compounds 1 and 2 are isostructural. Both crystallize in the monoclinic system with space group P21/c. Their structures are characterized as novel graphite-like layered structure with larger rings constructed by InO5Br polyhedra and the 1,4-benzendicarboxylate organic linkers. The used ILs cations [C6H11N2]+ are located between the layers and compensate for the negative charges of framework. Furthermore, their luminescent properties have also been studied.
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