Trends of phosphorus recovery technology from sewage sludge ash by wet chemical method

Minsun Lee, Dong-Jin Kim
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Abstract

Phosphorus (P) is a limited, essential, and irreplaceable nutrient for the biological activity of all the living organisms. Sewage sludge ash (SSA) is one of the most important secondary P resources due to its high P content. The SSA has been intensively investigated to recover P by wet chemicals (acid or alkali). Even though H2SO4 was mainly used to extract P because of its low cost and accessibility, the formation of CaSO4 (gypsum) hinders its use. Heavy metals in the SSA also cause a significant problem in P recovery since fertilizer needs to meet government standards for human health. Therefore, P recovery process with selective heavy metal removal needs to be developed. In this paper some of the most advanced P recovery processes have been introduced and discussed their technical characteristics. The results showed that further research is needed to identify the chemical mechanisms of P transformation in the recovery process and to increase P recovery efficiency and the yields.
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湿法化学法回收污泥灰磷技术发展趋势
磷(P)是一种有限的、必需的、不可替代的营养物质,对所有生物的生物活性都至关重要。污泥灰因其高磷含量而成为重要的二次磷资源之一。对湿化学剂(酸或碱)回收磷的SSA进行了深入的研究。尽管H2SO4因其成本低和可及性主要用于提取P,但CaSO4(石膏)的形成阻碍了其使用。由于肥料需要符合政府对人体健康的标准,SSA中的重金属也对磷的回收造成了重大问题。因此,需要开发选择性去除重金属的磷回收工艺。本文介绍了几种最先进的磷回收工艺,并对其技术特点进行了讨论。结果表明,需要进一步研究磷在回收过程中转化的化学机制,以提高磷的回收效率和收率。
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