LVG analysis of amidogen radical (NH2) found in interstellar medium and in cometary material

Q2 Physics and Astronomy Molecular Astrophysics Pub Date : 2019-06-01 DOI:10.1016/j.molap.2019.04.001
Mohit K. Sharma
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引用次数: 7

Abstract

Amidogen (NH2), a b-type asymmetric top molecule with electric dipole moment 1.82  ±  0.05 Debye, is detected in Sgr B2, in high-mass star-forming regions W31C (G10.6−0.4), W49N (G43.2−0.1), W51 (G49.5−0.4), G34.3+0.1, and in several comets. Because of two hydrogen atoms, each with nuclear spin 1/2, its rotational energy levels can be classified into ortho and para groups. We have not considered for fine structure splitting and hyper-fine structure splitting of rotational levels. For 15 rotational levels in the ground vibrational state, having energy up to 400 cm1, for each specie, the energies of rotational levels, and Einstein A and B coefficients for radiative transitions between the levels are calculated, using accurate values of spectroscopic data. These radiative transition probabilities along with the collisional rate coefficients (obtained from a scaling law) are employed as input parameters for solving a set of statistical equilibrium equations coupled with the equations of radiative transfer for each group. Several emission lines produced by amidogen are found. For each species of NH2, we have considered some strongest emission lines along with the observed one, which may help for identification of NH2 in the interstellar medium (ISM) and in the cometary material.

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星际介质和彗星物质中氨基自由基(NH2)的LVG分析
氨基根(NH2)是一种b型不对称的顶端分子,其电偶极矩为1.82 ± 0.05 Debye,在Sgr B2、高质量恒星形成区W31C (G10.6−0.4)、W49N (G43.2−0.1)、W51 (G49.5−0.4)、G34.3+0.1和一些彗星中都有发现。因为有两个氢原子,每个氢原子的核自旋为1/2,所以它的旋转能级可以分为邻位基和对位基。我们没有考虑转动能级的精细结构分裂和超精细结构分裂。对于15个处于地面振动状态的旋转能级,能量高达400 cm−1,对于每个物质,利用光谱数据的精确值计算了旋转能级的能量,以及能级之间辐射跃迁的爱因斯坦A和B系数。利用这些辐射跃迁概率和碰撞速率系数(由标度定律得到)作为输入参数,求解一组与每组辐射传递方程耦合的统计平衡方程。发现了几种由酰胺产生的发射谱线。对于每一种NH2,我们考虑了一些与观测到的最强发射线,这可能有助于识别星际介质(ISM)和彗星物质中的NH2。
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Molecular Astrophysics
Molecular Astrophysics ASTRONOMY & ASTROPHYSICS-
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期刊介绍: Molecular Astrophysics is a peer-reviewed journal containing full research articles, selected review articles, and thematic issues. Molecular Astrophysics is a new journal where researchers working in planetary and exoplanetary science, astrochemistry, astrobiology, spectroscopy, physical chemistry and chemical physics can meet and exchange their ideas. Understanding the origin and evolution of interstellar and circumstellar molecules is key to understanding the Universe around us and our place in it and has become a fundamental goal of modern astrophysics. Molecular Astrophysics aims to provide a platform for scientists studying the chemical processes that form and dissociate molecules, and control chemical abundances in the universe, particularly in Solar System objects including planets, moons, and comets, in the atmospheres of exoplanets, as well as in regions of star and planet formation in the interstellar medium of galaxies. Observational studies of the molecular universe are driven by a range of new space missions and large-scale scale observatories opening up. With the Spitzer Space Telescope, the Herschel Space Observatory, the Atacama Large Millimeter/submillimeter Array (ALMA), NASA''s Kepler mission, the Rosetta mission, and more major future facilities such as NASA''s James Webb Space Telescope and various missions to Mars, the journal taps into the expected new insights and the need to bring the various communities together on one platform. The journal aims to cover observational, laboratory as well as computational results in the galactic, extragalactic and intergalactic areas of our universe.
期刊最新文献
Chemistry on Interstellar Grain Surfaces Molecular Emission and Absorption Gas Phase Chemical Processes Diffuse Clouds Molecular Spectroscopy
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