Ion Exchange Synthesis and Structure of New Delafossite-Type CuInO2

M. Shimode, Y. Hayashi, M. Sasaki, K. Mukaida
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引用次数: 11

Abstract

New delafossite-type CuInO 2 was synthesized by ion exchange reaction of CuCl with α-NaFeO 2 -type NaInO 2 or with α-LiFeO 2 -type LiInO 2 . According to the XRD, after 144 h the main product obtained at 623 K was CuInO 2 in either starting material. Lattice parameters of CuInO 2 derived from NaInO 2 or LiInO 2 as determined by Rietveld analysis, are a = 329.01 pin, c = 1738.8 pm, and a = 329.22 pm, c = 1738.8 pm, respectively.
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新型delafosite型CuInO2的离子交换合成及结构
通过CuCl与α-NaFeO - 2型naino2或α- lifeo2型LiInO - 2离子交换反应,合成了新的延迟岩型CuInO - 2。XRD结果表明,在623 K下,144h后得到的主要产物均为CuInO 2。通过Rietveld分析,由naino2和LiInO 2得到的CuInO 2晶格参数分别为a = 329.01 pin, c = 1738.8 pm, a = 329.22 pm, c = 1738.8 pm。
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